ArticleChemical science2023
Degradable polyisoprene by radical ring-opening polymerization and application to polymer prodrug nanoparticles.
Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
8 citing papers in PubMed, 31 citations in OpenAlex.
- RAFT enables controlled radical ring-opening polymerisation of cyclic ketene acetals for degradable nanoparticles.Communications chemistry · 2026Article
- The successful impossible radical ring-opening copolymerization of thionolactones and methacrylates via an auxiliary third comonomer.Nature communications · 2025Article
- Main-Chain Scission of Acrylic Polymers via Intrachain Transesterification and Their Application in UV-curable Dismountable Adhesives.ACS polymers Au · 2025Article
- Single-Unit Comonomer Insertion Initiates Radical Polymerization of Thionolactone to Give Chemically and Thermally Degradable Polythioesters.Macromolecules · 2025Article
- Synthesis of Degradable Polystyrene and Its Derivative with In-Chain Thioester via Radical and Cationic Copolymerizations with a Seven-Membered Benzene-Fused Thionolactone.Polymer science & technology (Washington, D.C.) · 2025Article
- Topochemical Ring-Opening Polymerization of an Oxathianethione.Journal of the American Chemical Society · 2025Article
- Polysulfones Prepared by Radical Ring-Opening Polymerization of Cyclic Sulfolane Derivatives: Density Functional Theory Calculations, Synthesis, Structure, and Polymer Reactions.Materials (Basel, Switzerland) · 2025Article
- DegradableACS macro letters · 2024Article
Corrections and comments
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Authors and funding
7 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Radical ring-opening polymerization (rROP) has received renewed attention to incorporate cleavable linkages into the backbones of vinyl polymers, especially from cyclic ketene acetals (CKAs). Among the monomers that hardly copolymerize with CKAs are (1,3)-dienes such as isoprene (I). This is unfortunate since synthetic polyisoprene (PI) and its derivatives are the materials of choice for many applications, in particular as elastomers in the automotive, sport, footwear, and medical industries, but also in nanomedicine. Thionolactones have been recently proposed as a new class of rROP-compatible monomers for insertion of thioester units in the main chain. Herein, we report the synthesis of degradable PI by rROP
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What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.