Evidence map›Paper›PMID 36969451›Full record

ArticleACS omega2023

New Functional Polymer Materials via Click Chemistry-Based Modification of Cellulose Acetate.

Maximilian Röhrl, Justus F Ködel, Renee L Timmins, Christoph Callsen, Merve Aksit, Michael F Fink, Sebastian Seibt, Andy Weidinger, Glauco Battagliarin, Holger Ruckdäschel and 3 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in ACS omega, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors.

Maximilian RöhrlInorganic Chemistry 1, University of Bayreuth, Universitätsstrasse 30, 95440 Bayreuth, Germany.
Justus F KödelFachgruppe Chemie, Wirtschaftswissenschaftliches und Naturwissenschaftlich-Technologisches Gymnasium Bayreuth, Am Sportpark 1, 95448 Bayreuth, Germany.
Renee L TimminsInorganic Chemistry 1, University of Bayreuth, Universitätsstrasse 30, 95440 Bayreuth, Germany.
Christoph CallsenDepartment of Polymer Engineering, Faculty of Engineering Science, University of Bayreuth, Universitätsstrasse 30, 95440 Bayreuth, Germany.
Merve AksitDepartment of Polymer Engineering, Faculty of Engineering Science, University of Bayreuth, Universitätsstrasse 30, 95440 Bayreuth, Germany.
Michael F FinkChair of Electrochemical Process Engineering, Faculty of Engineering Science, University of Bayreuth, Universitätsstrasse 30, 95447 Bayreuth, Germany.ORCID https://orcid.org/0000-0002-2039-4735
Sebastian SeibtLinseis Messgeräte GmbH, Vielitzerstrasse 43, 95100 Selb, Germany.
Andy WeidingerFachgruppe Chemie, Wirtschaftswissenschaftliches und Naturwissenschaftlich-Technologisches Gymnasium Bayreuth, Am Sportpark 1, 95448 Bayreuth, Germany.
Glauco BattagliarinBiopolymers and Biodegradability Research, BASF, Carl-Bosch-Str. 38, 67056 Ludwigshafen am Rhein, Germany.
Holger RuckdäschelDepartment of Polymer Engineering, Faculty of Engineering Science, University of Bayreuth, Universitätsstrasse 30, 95440 Bayreuth, Germany.ORCID https://orcid.org/0000-0001-5985-2628
Rainer SchobertOrganic Chemistry 1, University of Bayreuth, Universitätsstrasse 30, 95440 Bayreuth, Germany.ORCID https://orcid.org/0000-0002-8413-4342
Josef BreuInorganic Chemistry 1, University of Bayreuth, Universitätsstrasse 30, 95440 Bayreuth, Germany.ORCID https://orcid.org/0000-0002-2547-3950
Bernhard BiersackOrganic Chemistry 1, University of Bayreuth, Universitätsstrasse 30, 95440 Bayreuth, Germany.ORCID https://orcid.org/0000-0001-7305-346X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Cellulose acetate (CA) was partially acrylated, and the resulting cellulose acetate acrylate (acryl-substitution degree of 0.2) underwent quantitative thio-Michael click reactions with various thiols. A toolbox of functional CA polymers was obtained in this way, and their properties were studied. The modification with fatty alkyl thiols led to hydrophobic materials with large water drop contact angles. Octadecylthio-, butoxycarbonylpropylthio-, and furanylthio-modifications formed highly transparent materials. The new derivative CAASFur disintegrated completely under industrial composting conditions. Films of modified CA polymers were cast and investigated in terms of barrier properties. The nanocomposite of CAAS18 compounded with a synthetic layered silicate (hectorite) of a large aspect ratio showed permeabilities as low as 0.09 g mm m

Identifiers

PMID36969451
PMCPMC10034841

What OpenQuestion holds

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LicenceCC BY-NC-ND
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.