ArticleNature communications2023
Arene C-H borylation strategy enabled by a non-classical boron cluster-based electrophile.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed, 17 citations in OpenAlex.
- Unwrapping the Dodecaborane Core: Structure, Electronic Properties, and Chemical Reactivity Across the Complete [BJournal of the American Chemical Society · 2026Article
- Single-iron catalyst with heterogenized TEMPO for selective toluene electrooxidation to benzaldehyde at low potentials.Nature communications · 2026Article
- Synergistic Fe/Ni catalysis for electrochemical 1,1-difunctionalization of alkenes.Nature communications · 2026Article
- Oxidation-induced nucleophilic substitution at the electron-rich B(12) vertex in [CBChemical science · 2025Article
- Leveraging long-lived arenium ions in superacid for meta-selective methylation.Nature communications · 2024Article
- Formation and reactivity of a unique M⋯C-H interaction stabilized by carborane cages.Chemical science · 2024Article
- Redox-Active Boron Clusters.Accounts of chemical research · 2024Article
- Decaborane: From Alfred Stock and Rocket Fuel Projects to Nowadays.Molecules (Basel, Switzerland) · 2023Review
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Authors and funding
7 authors at 3 institutions in 1 country.
Funding
Abstract
Introducing a tri-coordinate boron-based functional group (e.g., boronic ester) into an unactivated C-H bond in the absence of directing groups is an ongoing challenge in synthetic chemistry. Despite previous developments in transition metal-catalyzed and -free approaches, C-H borylation of sterically hindered arenes remains a largely unsolved problem to date. Here, we report a synthetic strategy of a two-step, precious metal-free electrophilic C-H borylation of sterically hindered alkyl- and haloarenes to generate aryl boronic esters. The first step relies on electrophilic aromatic substitution (EAS) induced by cage-opening of Cs
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Registered trials
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