ArticleBeilstein journal of organic chemistry2023
Synthesis and reactivity of azole-based iodazinium salts.
Article in Beilstein journal of organic chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Synthesis ofBeilstein journal of organic chemistry · 2024Article
- Oxidation of benzylic alcohols to carbonyls usingBeilstein journal of organic chemistry · 2024Article
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Authors and funding
4 authors.
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Abstract
A systematic investigation of imidazo- and pyrazoloiodazinium salts is presented. Besides a robust synthetic protocol that allowed us to synthesize these novel cyclic iodonium salts in their mono- and dicationic forms, we gained in-depth structural information through single-crystal analysis and demonstrated the ring opening of the heterocycle-bridged iodonium species. For an exclusive set of dicationic imidazoiodaziniums, we show highly delicate post-oxidation functionalizations retaining the hypervalent iodine center.
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