Evidence map›Paper›PMID 36939182›Full record

ArticleChemical communications (Cambridge, England)2023

Selective multi-electron aggregation at a hypervalent iodine center by sequential disproportionation.

Phong Thai, Brandon L Frey, Matthew T Figgins, Richard R Thompson, Raanan Carmieli, David C Powers

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical communications (Cambridge, England), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
  4. Article
  5. Iodanyl Radical Catalysis.Accounts of chemical research · 2023
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Phong ThaiDepartment of Chemistry, Texas A&M University, College Station, Texas 77843, USA. powers@chem.tamu.edu.ORCID http://orcid.org/0000-0001-6283-9344
Brandon L FreyDepartment of Chemistry, Texas A&M University, College Station, Texas 77843, USA. powers@chem.tamu.edu.ORCID http://orcid.org/0000-0002-6041-1659
Matthew T FigginsDepartment of Chemistry, Texas A&M University, College Station, Texas 77843, USA. powers@chem.tamu.edu.ORCID http://orcid.org/0000-0003-4391-3961
Richard R ThompsonDepartment of Chemistry, Texas A&M University, College Station, Texas 77843, USA. powers@chem.tamu.edu.ORCID http://orcid.org/0000-0002-2181-9846
Raanan CarmieliChemMatCARS, University of Chicago, Argonne, IL 60439, USA.ORCID http://orcid.org/0000-0003-4418-916X
David C PowersDepartment of Chemistry, Texas A&M University, College Station, Texas 77843, USA. powers@chem.tamu.edu.ORCID http://orcid.org/0000-0003-3717-2001

Funding

Metal-Free Electrocatalysis for Fine-Chemical SynthesisR35GM138114 · NIGMS · TEXAS A&M UNIVERSITY · PI David C Powers · 2020 to 2026
$2.2M
NIGMS NIH HHS R35 GM138114
6 · The paper itself

Abstract

We demonstrate that sequential disproportionation reactions can enable selective aggregation of two- or four electron-holes at a hypervalent iodine center. Disproportionation of an anodically generated iodanyl radical affords an iodosylbenzene derivative. Subsequent iodosylbenzene disproportionation can be triggered to provide access to an iodoxybenzene. These results demonstrate multielectron oxidation at the one-electron potential by selective and sequential disproportionation chemistry.

Identifiers

PMID36939182
PMCPMC10089653

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.