Evidence map›Paper›PMID 36937578›Full record

ArticleChemical science2023

Spin polarization assisted facile C-H activation by an

Jin Xiong, Qing Liu, Barbara Lavina, Michael Y Hu, Jiyong Zhao, Esen E Alp, Liang Deng, Shengfa Ye, Yisong Guo

Open access · diamondAbstract read
In one paragraph

Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
1.3field-weighted citation impact, top 23% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed, 9 citations in OpenAlex.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 4 institutions in 2 countries.

Jin XiongDepartment of Chemistry, Carnegie Mellon University Pittsburgh Pennsylvania 15213 USA ysguo@andrew.cmu.edu.ORCID https://orcid.org/0000-0001-7443-0554
Qing LiuState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences Shanghai 200032 P. R. China deng@sioc.ac.cn.ORCID https://orcid.org/0000-0002-3931-1442
Barbara LavinaAdvanced Photon Source, Argonne National Laboratory Argonne Illinois 60439 USA.ORCID https://orcid.org/0000-0002-8556-7916
Michael Y HuAdvanced Photon Source, Argonne National Laboratory Argonne Illinois 60439 USA.ORCID https://orcid.org/0000-0002-3718-7169
Jiyong ZhaoAdvanced Photon Source, Argonne National Laboratory Argonne Illinois 60439 USA.ORCID https://orcid.org/0000-0002-0777-3626
Esen E AlpAdvanced Photon Source, Argonne National Laboratory Argonne Illinois 60439 USA.
Liang DengState Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences Shanghai 200032 P. R. China deng@sioc.ac.cn.ORCID https://orcid.org/0000-0002-0964-9426
Shengfa YeState Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences Dalian 116023 P. R. China shengfa.ye@dicp.ac.cn.ORCID https://orcid.org/0000-0001-9747-1412
Yisong GuoDepartment of Chemistry, Carnegie Mellon University Pittsburgh Pennsylvania 15213 USA ysguo@andrew.cmu.edu.ORCID https://orcid.org/0000-0002-4132-3565
Argonne National Laboratory · USCarnegie Mellon University · USChinese Academy of Sciences · CNDalian Institute of Chemical Physics · CN

Funding

Understanding How Nonheme Iron-Dependent Enzymes Assemble Pharmacophores: Studies of Cyclopropane, Aziridine, and Isonitrile FormationR01GM127588 · NIGMS · NORTH CAROLINA STATE UNIVERSITY RALEIGH · PI Wei-chen Chang · 2018 to 2026
$3.3M
Elucidate Mechanisms of Quinolone Alkaloid Biosynthesis via Iron(II)/2-Oxoglutarate Dependent Enzymes: Diverse, but Controlled ReactivityR01GM125924 · NIGMS · CARNEGIE-MELLON UNIVERSITY · PI Yisong Guo · 2018 to 2026
$3.3M
NIGMS NIH HHS R01 GM125924NIGMS NIH HHS R01 GM127588
6 · The paper itself

Abstract

High valent iron terminal imido species (Fe[double bond, length as m-dash]NR) have been shown to be key reactive intermediates in C-H functionalization. However, the detailed structure-reactivity relationship in Fe[double bond, length as m-dash]NR species derived from studies of structurally well-characterized high-valent Fe[double bond, length as m-dash]NR complexes are still scarce, and the impact of imido N-substituents (electron-donating

Identifiers

PMID36937578
PMCPMC10016330
OpenAlexW4320902464

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.