Evidence map›Paper›PMID 36913585›Full record

ArticleProceedings of the National Academy of Sciences of the United States of America2023

Unexpected catalytic activity of nanorippled graphene.

P Z Sun, W Q Xiong, A Bera, I Timokhin, Z F Wu, A Mishchenko, M C Sellers, B L Liu, H M Cheng, E Janzen and 4 more

Full text read
In one paragraph

Article in Proceedings of the National Academy of Sciences of the United States of America, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.

0numbers the graph read from it
0cells of the map it votes in
17citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

17 citing papers in PubMed.

  1. Article
  2. Substrate-Tight Graphene Transmembrane-nanofluidic Devices.Small (Weinheim an der Bergstrasse, Germany) · 2026
    Article
  3. Article
  4. Adsorption and reaction of SOProceedings of the National Academy of Sciences of the United States of America · 2026
    Article
  5. Article
  6. Review
  7. Article
  8. Article
  9. Article
  10. Article
  11. Defects induce phase transition from dynamic to static rippling in graphene.Proceedings of the National Academy of Sciences of the United States of America · 2025
    Article
  12. Article
  13. Metal-Cation-Induced Tiny Ripple on Graphene.Nanomaterials (Basel, Switzerland) · 2024
    Article
  14. Article
  15. Article
  16. Graphene nanoripples enable unexpected catalytic reactivity.Proceedings of the National Academy of Sciences of the United States of America · 2023
    Article
  17. Anion-π catalysis on carbon allotropes.Beilstein journal of organic chemistry · 2023
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

14 authors.

P Z SunDepartment of Physics and Astronomy, University of Manchester, Manchester M13 9PL, UK.ORCID 0000-0002-5838-0945
W Q XiongKey Laboratory of Artificial Micro- and Nano- structures of Ministry of Education, School of Physics and Technology, Wuhan University, Wuhan 430072, China.
A BeraDepartment of Physics and Astronomy, University of Manchester, Manchester M13 9PL, UK.ORCID 0000-0003-2789-836X
I TimokhinDepartment of Physics and Astronomy, University of Manchester, Manchester M13 9PL, UK.
Z F WuDepartment of Physics and Astronomy, University of Manchester, Manchester M13 9PL, UK.
A MishchenkoDepartment of Physics and Astronomy, University of Manchester, Manchester M13 9PL, UK.
M C SellersDepartment of Physics and Astronomy, University of Manchester, Manchester M13 9PL, UK.
B L LiuShenzhen Graphene Center, Institute of Materials Research, Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, China.
H M ChengShenzhen Graphene Center, Institute of Materials Research, Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, China.
E JanzenTim Taylor Department of Chemical Engineering, Kansas State University, Manhattan, KS 66506.
J H EdgarTim Taylor Department of Chemical Engineering, Kansas State University, Manhattan, KS 66506.
I V GrigorievaDepartment of Physics and Astronomy, University of Manchester, Manchester M13 9PL, UK.
S J YuanKey Laboratory of Artificial Micro- and Nano- structures of Ministry of Education, School of Physics and Technology, Wuhan University, Wuhan 430072, China.
A K GeimDepartment of Physics and Astronomy, University of Manchester, Manchester M13 9PL, UK.ORCID 0000-0003-2861-8331

Funding

EC | European Research Council (ERC) 786532 VANDERLloyd's Register Foundation (LRF) Designer Nanomaterials
6 · The paper itself

Abstract

Graphite is one of the most chemically inert materials. Its elementary constituent, monolayer graphene, is generally expected to inherit most of the parent material's properties including chemical inertness. Here, we show that, unlike graphite, defect-free monolayer graphene exhibits a strong activity with respect to splitting molecular hydrogen, which is comparable to that of metallic and other known catalysts for this reaction. We attribute the unexpected catalytic activity to surface corrugations (nanoscale ripples), a conclusion supported by theory. Nanoripples are likely to play a role in other chemical reactions involving graphene and, because nanorippling is inherent to atomically thin crystals, can be important for two-dimensional (2D) materials in general.

Indexed as

2D materialscatalysisgraphenehydrogen dissociationproton transport

Identifiers

PMID36913585
PMCPMC10041176

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.