ArticleChemical science2023
Choose your leaving group: selective photodeprotection in a mixture of
Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
3 citing papers in PubMed.
- Wash-Free Multi-Target Super-Resolution Microscopy With Photocaged DNA Labels.Angewandte Chemie (International ed. in English) · 2026Article
- Far-field single-molecule vibrational spectroscopy and imaging.Chemical science · 2026Review
- Biomolecular infrared spectroscopy: making time for dynamics.Chemical science · 2024Review
Corrections and comments
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Photocages are light-triggerable molecular moieties that can locally release a pre-determined leaving group (LG). Finding a suitable photocage for a particular application may be challenging, as the choice may be limited by for instance the optical or physicochemical properties of the system. Using more than one photocage to release different LGs in a reaction mixture may even be more difficult. In this work an experimental strategy is presented that allows us to hand-pick the release of different LGs, and to do so in any order. This is achieved by using isotopologue photocage-LG mixtures in combination with ultrafast VIbrationally Promoted Electronic Resonance (VIPER) excitation. The latter provides the required molecular selectivity simply by tuning the wavenumber of the used IR pulses to the resonance of a specific photocage isotopologue, as is demonstrated here for the
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.