Evidence map›Paper›PMID 36904346›Full record

ReviewPolymers2023

The Polymers of Diethynylarenes-Is Selective Polymerization at One Acetylene Bond Possible? A Review.

Vyacheslav M Misin, Irina E Maltseva, Mark E Kazakov, Vladimir A Volkov

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In one paragraph

Review in Polymers, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Vyacheslav M MisinN.M. Emanuel Institute of Biochemical Physics, Russian Academy Science, 4 Kosygina Street, 119334 Moscow, Russia.
Irina E MaltsevaN.M. Emanuel Institute of Biochemical Physics, Russian Academy Science, 4 Kosygina Street, 119334 Moscow, Russia.ORCID 0000-0002-2905-3873
Mark E KazakovSPC UVICOM Ltd., 38A Olympic Avenue, 141009 Mytischi, Russia.
Vladimir A VolkovN.M. Emanuel Institute of Biochemical Physics, Russian Academy Science, 4 Kosygina Street, 119334 Moscow, Russia.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

In this review, all available publications on the polymerization of all isomers of bifunctional diethynylarenes due to the opening of C≡C bonds were considered and analyzed. It has been shown that with the use of polymers of diethynylbenzene, heat-resistant and ablative materials, catalysts, sorbents, humidity sensors, and other materials can be obtained. Various catalytic systems and conditions of polymer synthesis are considered. For the convenience of comparison, the publications considered are grouped according to common features, including the types of initiating systems. Critical consideration is given to the features of the intramolecular structure of the synthesized polymers since it determines the entire complex of properties of this material and subsequent materials. Branched and/or insoluble polymers are formed as a result of solid-phase and liquid-phase homopolymerization. It is shown that the synthesis of a completely linear polymer was carried out for the first time by anionic polymerization. The review considers in sufficient detail publications from hard-to-reach sources, as well as publications that required a more thorough critical examination. The review does not consider the polymerization of diethynylarenes with substituted aromatic rings because of their steric restrictions; the diethynylarenes copolymers with complex intramolecular structure; and diethynylarenes polymers obtained by oxidative polycondensation.

Indexed as

anionic polymerizationcatalytic activityclick reactionintramolecular structureliquid-phase polymerizationmodificationpoly-p-diethynylbenzenesolid-phase polymerizationstereoisomers

Identifiers

PMID36904346
PMCPMC10006943

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