Evidence map›Paper›PMID 36903703›Full record

ArticleNanomaterials (Basel, Switzerland)2023

Covalent Functionalization of Black Phosphorus Nanosheets with Dichlorocarbenes for Enhanced Electrocatalytic Hydrogen Evolution Reaction.

Aidar M Kuchkaev, Airat M Kuchkaev, Aleksander V Sukhov, Svetlana V Saparina, Oleg I Gnezdilov, Alexander E Klimovitskii, Sufia A Ziganshina, Irek R Nizameev, Iskander R Vakhitov, Alexey B Dobrynin and 5 more

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In one paragraph

Article in Nanomaterials (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

15 authors.

Aidar M KuchkaevArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov Street 8, 420088 Kazan, Russia.ORCID 0000-0001-5980-9865
Airat M KuchkaevArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov Street 8, 420088 Kazan, Russia.
Aleksander V SukhovArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov Street 8, 420088 Kazan, Russia.
Svetlana V SaparinaInstitute of Physics, Kazan Federal University, Kremlyovskaya Street 18, 420008 Kazan, Russia.ORCID 0000-0003-4039-4158
Oleg I GnezdilovInstitute of Physics, Kazan Federal University, Kremlyovskaya Street 18, 420008 Kazan, Russia.ORCID 0000-0003-4306-6272
Alexander E KlimovitskiiAlexander Butlerov Institute of Chemistry, Kazan Federal University, Kremlyovskaya Street 18, 420008 Kazan, Russia.
Sufia A ZiganshinaZavoisky Physical-Technical Institute, FRC Kazan Scientific Center of RAS, Sibirsky Tract 10/7, 420029 Kazan, Russia.
Irek R NizameevDepartment of Nanotechnologies in Electronics, Kazan National Research Technical University Named after A.N. Tupolev-KAI, K. Marx Street 10, 420111 Kazan, Russia.
Iskander R VakhitovInstitute of Physics, Kazan Federal University, Kremlyovskaya Street 18, 420008 Kazan, Russia.ORCID 0000-0003-4532-2911
Alexey B DobryninArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov Street 8, 420088 Kazan, Russia.
Dmitry I StoikovAlexander Butlerov Institute of Chemistry, Kazan Federal University, Kremlyovskaya Street 18, 420008 Kazan, Russia.
Gennady A EvtugynAlexander Butlerov Institute of Chemistry, Kazan Federal University, Kremlyovskaya Street 18, 420008 Kazan, Russia.
Oleg G SinyashinArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov Street 8, 420088 Kazan, Russia.
Xiongwu KangNew Energy Research Institute, School of Environment and Energy, South China University of Technology, Higher Education Mega Center, 382 East Waihuan Road, Guangzhou 510006, China.
Dmitry G YakhvarovArbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, Arbuzov Street 8, 420088 Kazan, Russia.ORCID 0000-0002-3906-8841

Funding

Government assignment for FRC Kazan Scientific Center of RAS not appropriateGrant for supporting of the Leading Scientific Schools 4078.2022.1.3Kazan Federal University Strategic Academic Leadership Program PRIORITY-2030
6 · The paper itself

Abstract

Two-dimensional black phosphorus (BP) has emerged as a perspective material for various micro- and opto-electronic, energy, catalytic, and biomedical applications. Chemical functionalization of black phosphorus nanosheets (BPNS) is an important pathway for the preparation of materials with improved ambient stability and enhanced physical properties. Currently, the covalent functionalization of BPNS with highly reactive intermediates, such as carbon-free radicals or nitrenes, has been widely implemented to modify the material's surface. However, it should be noted that this field requires more in-depth research and new developments. Herein, we report for the first time the covalent carbene functionalization of BPNS using dichlorocarbene as a functionalizing agent. The P-C bond formation in the obtained material (BP-CCl

Indexed as

black phosphoruscarbenecovalent functionalizationelectrocatalysishydrogen evolution reactionphosphorenereactive intermediates

Identifiers

PMID36903703
PMCPMC10005367

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.