Evidence map›Paper›PMID 36895514›Full record

ArticleCatalysis science & technology2023

Highly dispersed Rh single atoms over graphitic carbon nitride as a robust catalyst for the hydroformylation reaction.

Lole Jurado, Jerome Esvan, Ligia A Luque-Álvarez, Luis F Bobadilla, José A Odriozola, Sergio Posada-Pérez, Albert Poater, Aleix Comas-Vives, M Rosa Axet

Abstract read
In one paragraph

Article in Catalysis science & technology, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
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  5. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Lole JuradoCNRS, LCC (Laboratoire de Chimie de Coordination), UPS, INPT, Université de Toulouse 205 Route de Narbonne F-31077 Toulouse Cedex 4 France rosa.axet@lcc-toulouse.fr.ORCID https://orcid.org/0000-0003-1908-899X
Jerome EsvanCIRIMAT, CNRS-INPT-UPS, Université de Toulouse 4 Allée Emile Monso 31030 Toulouse France.
Ligia A Luque-ÁlvarezDepartamento de Química Inorgánica e Instituto de Ciencia de Materiales de Sevilla, Centro Mixto CSIC-Universidad de Sevilla Av. Américo Vespucio 49 41092 Sevilla Spain.ORCID https://orcid.org/0000-0002-3998-580X
Luis F BobadillaDepartamento de Química Inorgánica e Instituto de Ciencia de Materiales de Sevilla, Centro Mixto CSIC-Universidad de Sevilla Av. Américo Vespucio 49 41092 Sevilla Spain.ORCID https://orcid.org/0000-0003-0085-9811
José A OdriozolaDepartamento de Química Inorgánica e Instituto de Ciencia de Materiales de Sevilla, Centro Mixto CSIC-Universidad de Sevilla Av. Américo Vespucio 49 41092 Sevilla Spain.ORCID https://orcid.org/0000-0002-8283-0459
Sergio Posada-PérezInstitut de Química Computacional i Catàlisi and Departament de Química, Universitat de Girona c/ Maria Aurèlia Capmany 69 17003 Girona Catalonia Spain.
Albert PoaterInstitut de Química Computacional i Catàlisi and Departament de Química, Universitat de Girona c/ Maria Aurèlia Capmany 69 17003 Girona Catalonia Spain.ORCID https://orcid.org/0000-0002-8997-2599
Aleix Comas-VivesInstitute of Materials Chemistry, TU Wien 1060 Vienna Austria.ORCID https://orcid.org/0000-0002-7002-1582
M Rosa AxetCNRS, LCC (Laboratoire de Chimie de Coordination), UPS, INPT, Université de Toulouse 205 Route de Narbonne F-31077 Toulouse Cedex 4 France rosa.axet@lcc-toulouse.fr.ORCID https://orcid.org/0000-0002-2483-1533

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Rhodium-catalysed hydroformylation, effective tool in bulk and fine-chemical synthesis, predominantly uses soluble metal complexes. For that reason, the metal leaching and the catalyst recycling are still the major drawbacks of this process. Single-atom catalysts have emerged as a powerful tool to combine the advantages of both homogeneous and heterogeneous catalysts. Since using an appropriate support material is key to create stable, finely dispersed, single-atom catalysts, here we show that Rh atoms anchored on graphitic carbon nitride are robust catalysts for the hydroformylation reaction of styrene.

Identifiers

PMID36895514
PMCPMC9986719

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.