ArticleNature chemistry2023
Stepwise on-demand functionalization of multihydrosilanes enabled by a hydrogen-atom-transfer photocatalyst based on eosin Y.
Article in Nature chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed.
- Recyclable Pt-Catalyzed Biphase Hydrosilylation on Water: From Functionalized Monomers to Polymer Materials.Angewandte Chemie (International ed. in English) · 2026Article
- Incorporation of Organosilicon Motifs in Natural and Synthetic Small Molecules for Anticancer Therapeutics: Current Perspectives and Future Opportunities in Drug Design.Molecules (Basel, Switzerland) · 2026Review
- Dual-Quenching Charge Transfer Unlocks Record Nitrate-to-Ammonia Photocatalytic Conversion in Redox-Active Eosin Y Polymers.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Visible-Light-Mediated Metal-Free Desulfonylative Silylation for Alkenyl and Alkynylsilanes with Silacarboxylic Acids.ACS omega · 2026Article
- Photo-Mediated Silacyclization by Wavelength-Dependent Selective C─F or C─H Functionalization.Angewandte Chemie (International ed. in English) · 2025Article
- Electrochemical Deoxygenative Silylation of Alcohols.Angewandte Chemie (International ed. in English) · 2025Article
- Cyano group translocation to alkenyl C(spNature communications · 2025Article
- Synthesis of chiral germanium center enabled by poly-deborylative alkylation and desymmetrization.Nature communications · 2025Article
- Role of Hydrogen Transfer in Functional Molecular Materials and Devices.Precision chemistry · 2025Review
- Harnessing the β-boron effect for regioselective Ru-catalyzed hydrosilylation of internal alkynes.Nature communications · 2025Article
- Photo-induced ring-maintaining hydrosilylation of unactivated alkenes with hydrosilacyclobutanes.Nature communications · 2025Article
- De novo construction of amine-functionalized metal-organic cages as heterogenous catalysts for microflow catalysis.Nature communications · 2024Article
- Nickel/photoredox-catalyzed three-component silylacylation of acrylatesChemical science · 2024Article
- Dinuclear gold-catalyzed divergent dechlorinative radical borylation of gem-dichloroalkanes.Nature communications · 2024Article
- Ligand-modulated nickel-catalyzed regioselective silylalkylation of alkenes.Nature communications · 2023Article
- Article
- An Electrochemical Strategy to Synthesize Disilanes and Oligosilanes from Chlorosilanes.Angewandte Chemie (International ed. in English) · 2023Article
- Facile Synthesis of Sulfur-Containing Functionalized Disiloxanes with Nonconventional Fluorescence by Thiol-Epoxy Click Reaction.International journal of molecular sciences · 2023Article
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Authors and funding
16 authors.
Funding
Abstract
Organosilanes are of vital importance for modern human society, having found widespread applications in functional materials, organic synthesis, drug discovery and life sciences. However, their preparation remains far from trivial, and on-demand synthesis of heteroleptic substituted silicon reagents is a formidable challenge. The generation of silyl radicals from hydrosilanes via direct hydrogen-atom-transfer (HAT) photocatalysis represents the most atom-, step-, redox- and catalyst-economic pathway for the activation of hydrosilanes. Here, in view of the green characteristics of neutral eosin Y (such as its abundance, low cost, metal-free nature, absorption of visible light and excellent selectivity), we show that using it as a direct HAT photocatalyst enables the stepwise custom functionalization of multihydrosilanes, giving access to fully substituted silicon compounds. By exploiting this strategy, we realize preferable hydrogen abstraction of Si-H bonds in the presence of active C-H bonds, diverse functionalization of hydrosilanes (for example, alkylation, vinylation, allylation, arylation, deuteration, oxidation and halogenation), and remarkably selective monofunctionalization of di- and trihydrosilanes.
Identifiers
36894703What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.