Evidence map›Paper›PMID 36894545›Full record

ArticleNature communications2023

High-efficiency gold recovery by additive-induced supramolecular polymerization of β-cyclodextrin.

Huang Wu, Yu Wang, Chun Tang, Leighton O Jones, Bo Song, Xiao-Yang Chen, Long Zhang, Yong Wu, Charlotte L Stern, George C Schatz and 2 more

Open access · goldAbstract read
In one paragraph

Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.

0numbers the graph read from it
0cells of the map it votes in
9citing papers in PubMed
7.0field-weighted citation impact, top 2% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

9 citing papers in PubMed, 54 citations in OpenAlex.

  1. Article
  2. Review
  3. Article
  4. Article
  5. Review
  6. Article
  7. Article
  8. Article
  9. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors at 2 institutions in 3 countries.

Huang Wu *Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, 60208, USA.ORCID http://orcid.org/0000-0002-7429-0982
Yu Wang *Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, 60208, USA.ORCID http://orcid.org/0000-0002-0085-3308
Chun TangDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, 60208, USA.
Leighton O JonesDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, 60208, USA.ORCID http://orcid.org/0000-0001-6657-2632
Bo SongDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, 60208, USA.ORCID http://orcid.org/0000-0002-4337-848X
Xiao-Yang ChenDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, 60208, USA.ORCID http://orcid.org/0000-0003-3449-4136
Long ZhangDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, 60208, USA.ORCID http://orcid.org/0000-0002-4631-158X
Yong WuDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, 60208, USA.
Charlotte L SternDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, 60208, USA.ORCID http://orcid.org/0000-0002-9491-289X
George C SchatzDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, 60208, USA.ORCID http://orcid.org/0000-0001-5837-4740
Wenqi LiuDepartment of Chemistry, University of South Florida, 4202 East Fowler Avenue, Tampa, FL, 33620, USA. wenqi@usf.edu.ORCID http://orcid.org/0000-0001-6408-0204
J Fraser StoddartDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL, 60208, USA. stoddart@northwestern.edu.ORCID http://orcid.org/0000-0003-3161-3697
Northwestern University · USUniversity of South Florida · US

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Developing an eco-friendly, efficient, and highly selective gold-recovery technology is urgently needed in order to maintain sustainable environments and improve the utilization of resources. Here we report an additive-induced gold recovery paradigm based on precisely controlling the reciprocal transformation and instantaneous assembly of the second-sphere coordinated adducts formed between β-cyclodextrin and tetrabromoaurate anions. The additives initiate a rapid assembly process by co-occupying the binding cavity of β-cyclodextrin along with the tetrabromoaurate anions, leading to the formation of supramolecular polymers that precipitate from aqueous solutions as cocrystals. The efficiency of gold recovery reaches 99.8% when dibutyl carbitol is deployed as the additive. This cocrystallization is highly selective for square-planar tetrabromoaurate anions. In a laboratory-scale gold-recovery protocol, over 94% of gold in electronic waste was recovered at gold concentrations as low as 9.3 ppm. This simple protocol constitutes a promising paradigm for the sustainable recovery of gold, featuring reduced energy consumption, low cost inputs, and the avoidance of environmental pollution.

Identifiers

PMID36894545
PMCPMC9998620
OpenAlexW4323662985

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.