Evidence map›Paper›PMID 36873832›Full record

ArticleChemical science2023

Dynamic effects on ligand field from rapid hydride motion in an iron(ii) dimer with an

Sean F McWilliams, Brandon Q Mercado, K Cory MacLeod, Majed S Fataftah, Maxime Tarrago, Xiaoping Wang, Eckhard Bill, Shengfa Ye, Patrick L Holland

Abstract read
In one paragraph

Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Review
  2. Article
  3. Article
  4. Terminal Hydride Complex of High-Spin Mn.Journal of the American Chemical Society · 2024
    Article
  5. Article
  6. Partial Deoxygenative CO Homocoupling by a Diiron Complex.Angewandte Chemie (International ed. in English) · 2023
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Sean F McWilliamsDepartment of Chemistry, Yale University New Haven Connecticut USA patrick.holland@yale.edu.
Brandon Q MercadoDepartment of Chemistry, Yale University New Haven Connecticut USA patrick.holland@yale.edu.ORCID https://orcid.org/0000-0002-1940-3497
K Cory MacLeodDepartment of Chemistry, Yale University New Haven Connecticut USA patrick.holland@yale.edu.ORCID https://orcid.org/0000-0002-1361-1228
Majed S FataftahDepartment of Chemistry, Yale University New Haven Connecticut USA patrick.holland@yale.edu.
Maxime TarragoMax Planck Institute for Chemical Energy Conversion Mülheim an der Ruhr Germany.
Xiaoping WangNeutron Sciences Directorate, Oak Ridge National Laboratory Oak Ridge Tennessee USA.ORCID https://orcid.org/0000-0001-7143-8112
Eckhard BillMax Planck Institute for Chemical Energy Conversion Mülheim an der Ruhr Germany.
Shengfa YeMax Planck Institute for Chemical Energy Conversion Mülheim an der Ruhr Germany.ORCID https://orcid.org/0000-0001-9747-1412
Patrick L HollandDepartment of Chemistry, Yale University New Haven Connecticut USA patrick.holland@yale.edu.ORCID https://orcid.org/0000-0002-2883-2031

Funding

Low-Coordinate Synthetic Models for Nitrogenase ActivityR01GM065313 · NIGMS · YALE UNIVERSITY · PI PATRICK L HOLLAND · 2004 to 2026
$6.4M
NIGMS NIH HHS R01 GM065313
6 · The paper itself

Abstract

Hydride complexes are important in catalysis and in iron-sulfur enzymes like nitrogenase, but the impact of hydride mobility on local iron spin states has been underexplored. We describe studies of a dimeric diiron(ii) hydride complex using X-ray and neutron crystallography, Mössbauer spectroscopy, magnetism, DFT, and

Identifiers

PMID36873832
PMCPMC9977447

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.