ArticleJACS Au2023
Size Selective Ligand Tug of War Strategy to Separate Rare Earth Elements.
Article in JACS Au, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed, 57 citations in OpenAlex.
- Self-assembly drives rare-earth separations in a family of MChemical science · 2026Article
- On the Design of Effective Water-Soluble Actinide-Masking Ligands Through Ligand Structure Modulation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Macrocyclic Chelators for Aqueous Lanthanide Separations via Precipitation: Toward Sustainable Recycling of Rare-Earths from NdFeB Magnets.Journal of the American Chemical Society · 2025Article
- On the Importance of Configuration Search to the Predictivity of Lanthanide Selectivity.JACS Au · 2025Article
- Article
- Modulating metal-centered dimerization of a lanthanide chaperone protein for separation of light lanthanides.Proceedings of the National Academy of Sciences of the United States of America · 2024Article
- Amino Acid Decorated Phenanthroline Diimide as Sustainable Hydrophilic Am(III) Masking Agent with High Acid Resistance.JACS Au · 2024Article
- Tetradentate Ligand's Chameleon-Like Behavior Offers Recognition of Specific Lanthanides.Journal of the American Chemical Society · 2024Article
- Insights into coordination and ligand trends of lanthanide complexes from the Cambridge Structural Database.Scientific reports · 2024Article
- Observation of a promethium complex in solution.Nature · 2024Article
- Article
- A Simple yet Efficient Hydrophilic Phenanthroline-Based Ligand for Selective Am(III) Separation under High Acidity.ACS central science · 2023Article
- Combining Copper and Zinc into a Biosensor for Anti-Chemoresistance and Achieving Osteosarcoma Therapeutic Efficacy.Molecules (Basel, Switzerland) · 2023Review
Corrections and comments
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Authors and funding
5 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Separating rare earth elements is a daunting task due to their similar properties. We report a "tug of war" strategy that employs a lipophilic and hydrophilic ligand with contrasting selectivity, resulting in a magnified separation of target rare earth elements. Specifically, a novel water-soluble bis-lactam-1,10-phenanthroline with an affinity for light lanthanides is coupled with oil-soluble diglycolamide that selectively binds heavy lanthanides. This two-ligand strategy yields a quantitative separation of the lightest (e.g., La-Nd) and heaviest (e.g., Ho-Lu) lanthanides, enabling efficient separation of neighboring lanthanides in-between (e.g., Sm-Dy).
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.