Evidence map›Paper›PMID 36866600›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2023

No Transition Metals Required - Oxygen Promoted Synthesis of Imines from Primary Alcohols and Amines under Ambient Conditions.

Daniel Himmelbauer, Radu Talmazan, Stefan Weber, Jan Pecak, Antonio Thun-Hohenstein, Maxine-Sophie Geissler, Lukas Pachmann, Marc Pignitter, Maren Podewitz, Karl Kirchner

Open access · hybridAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.8field-weighted citation impact, top 33% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 8 citations in OpenAlex.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors at 2 institutions in 1 country.

Daniel HimmelbauerInstitute of Applied Synthetic Chemistry, TU Wien, Getreidemarkt 9/163-AC, A-1060, Wien, Austria.
Radu TalmazanInstitute of Materials Chemistry, TU Wien, Getreidemarkt 9, A-1060, Wien, Austria.ORCID http://orcid.org/0000-0001-6678-7801
Stefan WeberInstitute of Applied Synthetic Chemistry, TU Wien, Getreidemarkt 9/163-AC, A-1060, Wien, Austria.ORCID http://orcid.org/0000-0002-1777-0971
Jan PecakInstitute of Applied Synthetic Chemistry, TU Wien, Getreidemarkt 9/163-AC, A-1060, Wien, Austria.ORCID http://orcid.org/0000-0003-1431-3430
Antonio Thun-HohensteinInstitute of Applied Synthetic Chemistry, TU Wien, Getreidemarkt 9/163-AC, A-1060, Wien, Austria.
Maxine-Sophie GeisslerInstitute of Applied Synthetic Chemistry, TU Wien, Getreidemarkt 9/163-AC, A-1060, Wien, Austria.
Lukas PachmannInstitute of Applied Synthetic Chemistry, TU Wien, Getreidemarkt 9/163-AC, A-1060, Wien, Austria.
Marc PignitterDepartment of Physiological Chemistry, Faculty of Chemistry, University of Vienna, Althanstrasse 14, 1090, Wien, Austria.ORCID http://orcid.org/0000-0002-5793-8572
Maren PodewitzInstitute of Materials Chemistry, TU Wien, Getreidemarkt 9, A-1060, Wien, Austria.ORCID http://orcid.org/0000-0001-7256-1219
Karl KirchnerInstitute of Applied Synthetic Chemistry, TU Wien, Getreidemarkt 9/163-AC, A-1060, Wien, Austria.ORCID http://orcid.org/0000-0003-0872-6159
TU Wien · ATUniversity of Vienna · AT

Funding

Austrian Science Fund P32570-NAustrian Science Fund P33016-NAustrian Science Fund P33528
6 · The paper itself

Abstract

The synthesis of imines denotes a cornerstone in organic chemistry. The use of alcohols as renewable substituents for carbonyl-functionality represents an attractive opportunity. Consequently, carbonyl moieties can be in situ generated from alcohols upon transition-metal catalysis under inert atmosphere. Alternatively, bases can be utilized under aerobic conditions. In this context, we report the synthesis of imines from benzyl alcohols and anilines, promoted by KO

Indexed as

DFTiminesoxidation reactionsradical mechanismstransition metal free

Identifiers

PMID36866600
PMCPMC10946877
OpenAlexW4323036361

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.