Ligand vacancy channels in pillared inorganic-organic hybrids for electrocatalytic organic oxidation with enzyme-like activities.

Zhe Chen, Jili Li, Lingshen Meng, Jianan Li, Yaming Hao, Tao Jiang, Xuejing Yang, Yefei Li, Zhi-Pan Liu, Ming Gong

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Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

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2citing papers in PubMed

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3 · Its place in the literature

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2 citing papers in PubMed.

Defect-Driven Accelerated Reconstruction of Metal-Organic Frameworks Toward High-Performance Anion Exchange Membrane Water Electrolysis.Small (Weinheim an der Bergstrasse, Germany) · 2026
Article
Design of metamagnetic layered cobalt(II) coordination polymers with controlled magnetic phase transitions.Frontiers in chemistry · 2026
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5 · Who and what money

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10 authors.

Zhe Chen *Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200438, China.

Jili Li *Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200438, China.

Lingshen MengDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200438, China.

Jianan LiNational Engineering Laboratory for Industrial Wastewater Treatment, East China University of Science and Technology, Shanghai, 200237, China.

Yaming HaoDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200438, China.

Tao JiangDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200438, China.

Xuejing YangNational Engineering Laboratory for Industrial Wastewater Treatment, East China University of Science and Technology, Shanghai, 200237, China.ORCID http://orcid.org/0000-0001-5144-4400

Yefei LiDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200438, China. yefeil@fudan.edu.cn.ORCID http://orcid.org/0000-0003-4433-7433

Zhi-Pan LiuDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200438, China.ORCID http://orcid.org/0000-0002-2906-5217

Ming GongDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai, 200438, China. gongm@fudan.edu.cn.ORCID http://orcid.org/0000-0002-1584-1211

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Simultaneously achieving abundant and well-defined active sites with high selectivity has been one of the ultimate goals for heterogeneous catalysis. Herein, we construct a class of Ni hydroxychloride-based inorganic-organic hybrid electrocatalysts with the inorganic Ni hydroxychloride chains pillared by the bidentate N-N ligands. The precise evacuation of N-N ligands under ultrahigh-vacuum forms ligand vacancies while partially retaining some ligands as structural pillars. The high density of ligand vacancies forms the active vacancy channel with abundant and highly-accessible undercoordinated Ni sites, exhibiting 5-25 fold and 20-400 fold activity enhancement compared to the hybrid pre-catalyst and standard β-Ni(OH)

Identifiers

PMID36864050

DOI10.1038/s41467-023-36830-4

PMCPMC9981682

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