ArticleCommunications chemistry2023
In situ single-crystal synchrotron X-ray diffraction studies of biologically active gases in metal-organic frameworks.
Article in Communications chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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Who cites it
8 citing papers in PubMed.
- Facile Electrodeposition Preparation of Low-Cost and High-Activity Nickel-Based Hydrogen Evolution Catalysts.Nanomaterials (Basel, Switzerland) · 2026Article
- Crystallographic visualization of C3-hydrocarbon-induced structural transformation and guest encapsulation within a flexible coordination network.Chemical science · 2026Article
- Harnessing the structural evolution of metal-organic frameworks under electrocatalytic conditions.Communications chemistry · 2025Review
- In Situ Single-Crystal X-ray Diffraction Studies of an Anomalous Nitric Oxide Adsorption in a Partially Activated Metal-Organic Framework.Journal of the American Chemical Society · 2025Article
- Dual-Action NO Delivery from One Mixed Metal Metal-Organic Framework.Inorganic chemistry · 2025Article
- Article
- Mixed Metal-Organic Framework Mixed-Matrix Membranes: Insights into Simultaneous Moisture-Triggered and Catalytic Delivery of Nitric Oxide using Cryo-scanning Electron Microscopy.ACS applied materials & interfaces · 2023Article
- Green Ultrasound-Assisted Synthesis of Rare-Earth-Based MOFs.Molecules (Basel, Switzerland) · 2023Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
Metal-organic frameworks (MOFs) are well known for their ability to adsorb various gases. The use of MOFs for the storage and release of biologically active gases, particularly nitric oxide (NO) and carbon monoxide (CO), has been a subject of interest. To elucidate the binding mechanisms and geometry of these gases, an in situ single crystal X-ray diffraction (scXRD) study using synchrotron radiation at Diamond Light Source has been performed on a set of MOFs that display promising gas adsorption properties. NO and CO, were introduced into activated Ni-CPO-27 and the related Co-4,6-dihydroxyisophthalate (Co-4,6-dhip). Both MOFs show strong binding affinity towards CO and NO, however CO suffers more from competitive co-adsorption of water. Additionally, we show that morphology can play an important role in the ease of dehydration for these two systems.
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Registered trials
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