Electronic and Magnetic Properties of a Three-Arm Nonconjugated Open-Shell Macromolecule.

Nonconjugated radical polymers (i.e., macromolecules with aliphatic backbones that have stable open-shell sites along their pendant groups) have arisen as an intriguing complement to π-conjugated polymers in organic electronic devices and may prove to have superior properties in magneto-responsive applications. To date, however, the design of nonconjugated radical polymers has primarily focused on linear homopolymer, copolymer, and block polymer motifs even though conjugated dendritic macromolecules (i.e., polyradicals) have shown significant promise in terms of their response under applied magnetic fields. Here, we address this gap in creating a nonconjugated, three-arm radical macromolecule with nitroxide open-shell sites using a straightforward, single-step reaction, and we evaluated the electronic and magnetic properties of this material using a combined computational and experimental approach. The synthetic approach employed resulted in a high-purity macromolecule with a well-defined molecular weight and narrow molecular weight distribution. Moreover, epoxide-based units were implemented in the three-arm radical macromolecule design, and this resulted in a nonlinear radical macromolecule with a low (i.e., below room temperature) glass transition temperature and one that was an amorphous material in the solid state. These properties allowed thin films of the three-arm radical macromolecule to have electrical conductivity values on par with many linear radical polymers previously reported, and our computational efforts suggest the potential of higher generation open-shell dendrimers to achieve advanced electronic and magnetic properties. Importantly, the three-arm radical macromolecule also demonstrated antiferromagnetic exchange coupling between spins at temperatures < 10 K. In this way, this effort puts forward key structure-property relationships in nonlinear radical macromolecules and presents a clear path for the creation of next-generation macromolecules of this type.