ArticleACS organic & inorganic Au2022
Porphyrins as Promising Photocatalysts for Red-Light-Induced Functionalizations of Biomolecules.
Article in ACS organic & inorganic Au, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 24 papers.
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Who cites it
24 citing papers in PubMed, 50 citations in OpenAlex.
- Selenoxanthylium Salts─Organic Photocatalysts for Low-Energy Photoredox Catalysis.Journal of the American Chemical Society · 2026Article
- Red-Light Photoredox C-H Alkylation of Acceptor Heterocycles Enabled by Substoichiometric NADH.Organic letters · 2026Article
- Room temperature photochemical synthesis of metal-organic frameworks for enhanced photocatalysis.Nature communications · 2026Article
- Predictive, Data-Driven Design of Red-Light Photoredox Catalysts for C─Heteroatom Bond Formation.Angewandte Chemie (International ed. in English) · 2026Article
- Red-Light-Induced Cysteine Modifications Suitable for Protein Labeling.ACS organic & inorganic Au · 2025Article
- Red-Light-Mediated Generation of Radicals: Applications in Organic Synthesis, Small-Molecule Activation, Polymerization, and Bio-Related Fields.Angewandte Chemie (International ed. in English) · 2025Review
- A Universal Approach to Anchoring Chromophores onto Magnetic Scaffold for Achieving Easily Recyclable Heterogeneous Photocatalytic Systems.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Red Light and Supersilane: A Novel Pathway for Hydrofunctionalizations and Giese Reactions.ACS organic & inorganic Au · 2025Article
- Red-Light-ActiveJournal of the American Chemical Society · 2025Article
- Low-energy photoredox catalysis.Nature reviews. Chemistry · 2025Review
- Red light excitation: illuminating photocatalysis in a new spectrum.Beilstein journal of organic chemistry · 2025Review
- Singlets-Driven Photoredox Catalysts: Transforming Noncatalytic Red Fluorophores to Efficient Catalysts.JACS Au · 2024Article
- Substituent Effects in the Photophysical and Electrochemical Properties of Meso-Tetraphenylporphyrin Derivatives.Molecules (Basel, Switzerland) · 2024Article
- Catalytic Protein Inhibitors.Angewandte Chemie (International ed. in English) · 2024Review
- Transformations of carbohydrate derivatives enabled by photocatalysis and visible light photochemistry.Chemical science · 2024Review
- Advances in the use of metal-free tetrapyrrolic macrocycles as catalysts.Beilstein journal of organic chemistry · 2024Review
- Photochemical Transformations of Diverse Biologically Active Resveratrol Analogs in Batch and Flow Reactors.Molecules (Basel, Switzerland) · 2023Article
- Enhancing Visible-Light Photocatalysis with Pd(II) Porphyrin-Based TiOMolecules (Basel, Switzerland) · 2023Article
- Red-light-mediated Barton decarboxylation reaction and one-pot wavelength-selective transformations.Chemical science · 2023Article
- Surface-decorated porphyrinic zirconium-based metal-organic frameworks (MOFs) using post-synthetic self-assembly for photodegradation of methyl orange dye.RSC advances · 2023Article
Corrections and comments
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Authors and funding
6 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Red-light enables deeper material penetration, which is important for biological applications and has consequences for chemical synthesis. Therefore, the search for new photocatalysts that absorb in this region is crucial. Despite the undeniable utility of porphyrins in blue- and green-light-induced energy- and electron-transfer processes, they are also perfectly suited for red-light applications. Herein, we describe free-base porphyrins as photoredox catalysts for red-light-induced organic transformations. They can act as both photooxidants and photoreductants and can accomplish the synthesis of biaryls once merged with Pd-catalysis. The developed methodology holds promise for broader applications, as the heme-based protoporphyrin is used as a photocatalyst and reactions can be realized in aqueous conditions.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.