Evidence map›Paper›PMID 36855668›Full record

ArticleACS organic & inorganic Au2022

Alternatives to Iridium: A Polyaza[7]helicene as a Strongly Reductive Visible Light Photoredox Catalyst.

Johannes Rocker, Till Opatz

Abstract read
In one paragraph

Article in ACS organic & inorganic Au, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

Johannes RockerDepartment of Chemistry, Johannes Gutenberg University, Duesbergweg 10-14, 55128 Mainz, Germany.ORCID https://orcid.org/0000-0001-8334-3807
Till OpatzDepartment of Chemistry, Johannes Gutenberg University, Duesbergweg 10-14, 55128 Mainz, Germany.ORCID https://orcid.org/0000-0002-3266-4050

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The use of a readily accessible polyazahelicene as a strongly reducing metal-free alternative to the commonly used precious metal based photoredox catalysts is demonstrated. An improved two-step synthesis of the catalyst is described, and its photophysical properties with respect to its use as a photoredox catalyst are evaluated. Its activity under visible light irradiation is proven by application in two double radical light-driven multicomponent reactions. The azahelicene gave comparable results to an iridium-based catalyst originally used for the same transformations.

Identifiers

PMID36855668
PMCPMC9955290

What OpenQuestion holds

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LicenceCC BY-NC-ND
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.