Evidence map›Paper›PMID 36855666›Full record

ReviewACS organic & inorganic Au2022

Evolution of Triangular All-Metal Aromatic Complexes from Bonding Quandaries to Powerful Catalytic Platforms.

Franca Bigi, Daniele Cauzzi, Nicola Della Ca', Max Malacria, Raimondo Maggi, Elena Motti, Yanlan Wang, Giovanni Maestri

Abstract readReview
In one paragraph

Review in ACS organic & inorganic Au, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
  4. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Franca BigiDepartment of Chemistry, Life Sciences and Environmental Sustainability, Università di Parma, Parco Area delle Scienze 17/A, 43124 Parma, Italy.
Daniele CauzziDepartment of Chemistry, Life Sciences and Environmental Sustainability, Università di Parma, Parco Area delle Scienze 17/A, 43124 Parma, Italy.
Nicola Della Ca'Department of Chemistry, Life Sciences and Environmental Sustainability, Università di Parma, Parco Area delle Scienze 17/A, 43124 Parma, Italy.ORCID https://orcid.org/0000-0002-7853-7954
Max MalacriaFaculty of Science and Engineering, IPCM, UMR CNRS 8232, Sorbonne Université, 4 place Jussieu, Paris 75252 Cedex 05, France.ORCID https://orcid.org/0000-0002-3563-3508
Raimondo MaggiDepartment of Chemistry, Life Sciences and Environmental Sustainability, Università di Parma, Parco Area delle Scienze 17/A, 43124 Parma, Italy.ORCID https://orcid.org/0000-0003-3811-7186
Elena MottiDepartment of Chemistry, Life Sciences and Environmental Sustainability, Università di Parma, Parco Area delle Scienze 17/A, 43124 Parma, Italy.
Yanlan WangDepartment of Chemistry and Chemical Engineering, Liaocheng University, 252059 Liaocheng, China.
Giovanni MaestriDepartment of Chemistry, Life Sciences and Environmental Sustainability, Università di Parma, Parco Area delle Scienze 17/A, 43124 Parma, Italy.ORCID https://orcid.org/0000-0002-0244-8605

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

This manuscript describes an overview on the literature detailing the observation of trinuclear complexes that present delocalized metal-metal bonds similar to those of regular aromatics, which are formed combining main group elements. A particular emphasis is given to the structural and electronic features of aromatic clusters that are sufficiently stable to allow their isolation. In parallel to the description of their key bonding properties, the work presents reported catalytic applications of these complexes, which already span from elaborated C-C-forming cascades to highly efficient cross-coupling methods. These examples present peculiar aspects of the unique reactivity exerted by all-metal aromatic complexes, which can often be superior to their established, popular mononuclear peers in terms of chemoselectivity and chemical robustness.

Identifiers

PMID36855666
PMCPMC9955218

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.