Evidence map›Paper›PMID 36855530›Full record

ArticleACS organic & inorganic Au2022

Substituent-Induced Control of

Ulises Carrillo, Antonio Francés-Monerris, Anil Reddy Marri, Cristina Cebrián, Philippe C Gros

Open access · goldAbstract read
In one paragraph

Article in ACS organic & inorganic Au, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
0.2field-weighted citation impact, top 53% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 3 citations in OpenAlex.

  1. Synthetic Mechanism of a Fe(II)Inorganic chemistry · 2026
    Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 2 institutions in 2 countries.

Ulises CarrilloUniversité de Lorraine, CNRS, L2CM, F-57000 Metz, France.
Antonio Francés-MonerrisDepartament de Química Física, Universitat de València, 46100 Burjassot, Spain.ORCID https://orcid.org/0000-0001-8232-4989
Anil Reddy MarriUniversité de Lorraine, CNRS, L2CM, F-54000 Nancy, France.
Cristina CebriánUniversité de Lorraine, CNRS, L2CM, F-57000 Metz, France.ORCID https://orcid.org/0000-0002-1773-6722
Philippe C GrosUniversité de Lorraine, CNRS, L2CM, F-54000 Nancy, France.ORCID https://orcid.org/0000-0003-4905-1581
Centre National de la Recherche Scientifique · FRUniversitat de València · ES

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The stereoselective synthesis of geometrical iron(II) complexes bearing azine-NHC ligands is described. Facial and meridional selectivity is achieved as a function of the steric demand of the azine unit, with no remarkable influence of the carbene nature. More specifically, meridional complexes are obtained upon selecting bulky 5-mesityl-substituted pyridyl coordinating units. Unexpectedly, increase of the steric hindrance in the α position with respect to the N coordinating atom results in an exclusive facial configuration, which is in stark contrast to the meridional selectivity induced by other reported α-substituted bidentate ligands. Investigation of the structure and the optical and electrochemical properties of the here-described complexes has revealed the non-negligible effect of the

Identifiers

PMID36855530
PMCPMC9955161
OpenAlexW4297498753

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.