Evidence map›Paper›PMID 36855471›Full record

ArticleACS organic & inorganic Au2022

Boosting Gold(I) Catalysis via Weak Interactions: New Fine-Tunable Impy Ligands.

Riccardo Pedrazzani, Angela Pintus, Roberta De Ventura, Marianna Marchini, Paola Ceroni, Carlos Silva López, Magda Monari, Marco Bandini

Abstract read
In one paragraph

Article in ACS organic & inorganic Au, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Article
  2. Article
  3. Chiral Imidazo[1,5‑JACS Au · 2025
    Article
  4. Article
  5. Article
  6. Article
  7. [Au(NpCatalysis science & technology · 2023
    Article
  8. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Riccardo PedrazzaniDipartimento di Chimica "Giacomo Ciamician", Alma Mater Studiorum, Via Selmi 2, 40126 Bologna, Italy.
Angela PintusDipartimento di Chimica "Giacomo Ciamician", Alma Mater Studiorum, Via Selmi 2, 40126 Bologna, Italy.
Roberta De VenturaDipartimento di Chimica "Giacomo Ciamician", Alma Mater Studiorum, Via Selmi 2, 40126 Bologna, Italy.
Marianna MarchiniDipartimento di Chimica "Giacomo Ciamician", Alma Mater Studiorum, Via Selmi 2, 40126 Bologna, Italy.ORCID https://orcid.org/0000-0002-9746-2062
Paola CeroniDipartimento di Chimica "Giacomo Ciamician", Alma Mater Studiorum, Via Selmi 2, 40126 Bologna, Italy.ORCID https://orcid.org/0000-0001-8916-1473
Carlos Silva LópezDepartamento de Química Orgánica, Universidad de Vigo, 36310 Vigo, Spain.ORCID https://orcid.org/0000-0003-4955-9844
Magda MonariDipartimento di Chimica "Giacomo Ciamician", Alma Mater Studiorum, Via Selmi 2, 40126 Bologna, Italy.
Marco BandiniDipartimento di Chimica "Giacomo Ciamician", Alma Mater Studiorum, Via Selmi 2, 40126 Bologna, Italy.ORCID https://orcid.org/0000-0001-9586-3295

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

A series of modular ImPy-carbene-Au(I) complexes are synthesized and fully characterized both in the solid state and in solution. The presence of oligoaryl units (phenyl and thienyl rings) at the C5-position of the ImPy core (in close proximity to the gold center) imprints on the organometallic species fine-tunable and predictable catalytic properties. A marked accelerating effect was recorded in several [Au(I)]-catalyzed electrophilic activations of unsaturated hydrocarbons when a CF

Identifiers

PMID36855471
PMCPMC9954282

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.