Evidence map›Paper›PMID 36850338›Full record

ArticlePolymers2023

Synthesis and Design of Hybrid Metalloporphyrin Polymers Based on Palladium (II) and Copper (II) Cations and Axial Complexes of Pyridyl-Substituted Sn(IV)Porphyrins with Octopamine.

Anastasia E Likhonina, Galina M Mamardashvili, Ilya A Khodov, Nugzar Z Mamardashvili

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Polymers, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Anastasia E LikhoninaG.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, Akademicheskaya St.1P, 153045 Ivanovo, Russia.
Galina M MamardashviliG.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, Akademicheskaya St.1P, 153045 Ivanovo, Russia.
Ilya A KhodovG.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, Akademicheskaya St.1P, 153045 Ivanovo, Russia.ORCID 0000-0003-2439-9290
Nugzar Z MamardashviliG.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, Akademicheskaya St.1P, 153045 Ivanovo, Russia.

Funding

Russian Science Foundation 22-23-00018
6 · The paper itself

Abstract

Supramolecular metalloporphyrin polymers formed by binding tetrapyrrolic macrocycle peripheral nitrogen atoms to Pd(II) cations and Sn(IV)porphyrins extra-ligands reaction centers to Cu(II) cations were obtained and identified. The structure and the formation mechanism of obtained hydrophobic Sn(IV)-porphyrin oligomers and polymers in solution were established, and their resistance to UV radiation and changes in solution temperature was studied. It was shown that the investigated polyporphyrin nanostructures are porous materials with predominance cylindrical mesopores. Density functional theory (DFT) was used to geometrically optimize the experimentally obtained supramolecular porphyrin polymers. The sizes of unit cells in porphyrin tubular structures were determined and coincided with the experimental data. The results obtained can be used to create highly porous materials for separation, storage, transportation, and controlled release of substrates of different nature, including highly volatile, explosive, and toxic gases.

Indexed as

highly porous materialsphotoresistanceporphyrin polymersSn(IV)porphyrin extra-complexesthermal stability

Identifiers

PMID36850338
PMCPMC9959591

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