Evidence map›Paper›PMID 36838561›Full record

ArticleMolecules (Basel, Switzerland)2023

Two-Photon Absorption and Multiphoton Excited Fluorescence of Acetamide-Chalcone Derivatives: The Role of Dimethylamine Group on the Nonlinear Optical and Photophysical Properties.

André Gasparotto Pelosi, Eli Silveira-Alves, Leandro Henrique Zucolotto Cocca, João Victor Valverde, Guilherme Roberto Oliveira, Daniel Luiz da Silva, Leonardo De Boni, Pablo José Gonçalves, Cleber Renato Mendonca

Abstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

André Gasparotto PelosiSão Carlos Institute of Physics, University of São Paulo, São Carlos 13566-590, SP, Brazil.
Eli Silveira-AlvesInstitute of Chemistry, Federal University of Goiás, Goiânia 74690-900, GO, Brazil.ORCID 0000-0002-8117-3127
Leandro Henrique Zucolotto CoccaSão Carlos Institute of Physics, University of São Paulo, São Carlos 13566-590, SP, Brazil.ORCID 0000-0003-4587-4062
João Victor ValverdeSão Carlos Institute of Physics, University of São Paulo, São Carlos 13566-590, SP, Brazil.
Guilherme Roberto OliveiraInstitute of Chemistry, Federal University of Goiás, Goiânia 74690-900, GO, Brazil.
Daniel Luiz da SilvaDepartment of Natural Sciences, Mathematics and Education, Federal University of São Carlos, Araras 13604-900, SP, Brazil.ORCID 0000-0002-1287-4210
Leonardo De BoniSão Carlos Institute of Physics, University of São Paulo, São Carlos 13566-590, SP, Brazil.ORCID 0000-0002-1875-1852
Pablo José GonçalvesInstitute of Chemistry, Federal University of Goiás, Goiânia 74690-900, GO, Brazil.ORCID 0000-0003-0246-1073
Cleber Renato MendoncaSão Carlos Institute of Physics, University of São Paulo, São Carlos 13566-590, SP, Brazil.ORCID 0000-0001-6672-2186

Funding

Air Force Office of Scientific Research FA9550-12-1-0028Army Research Laboratory W911NF-21-1-0362Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) 310200/2021-0Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) 001Fundação de Amparo à Pesquisa do Estado de Goiás (FAPEG) 201410267001776 and 201710267000533Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) 2011/12399-0, 2015/20032-0 2016/20886-1 and 2018/11283-7
6 · The paper itself

Abstract

This work studied the effect of different electron-withdrawing and electron-donating groups on the linear and nonlinear optical properties of acetamide-chalcone derivatives. The results showed that the addition of the dimethylamine group led to a large fluorescence emission (71% of fluorescence quantum yield in DMSO solution) that can be triggered by two and three-photon excitations, which is essential for biological applications. Furthermore, dimethylamine also red-shifts the lower energy state by approximately 90 nm, increasing the two-photon absorption cross-section of the lower energy band by more than 100% compared with the other studied compounds. All compounds presented two-electronic states observed through one and two-photon absorption spectroscopy and confirmed by Quantum Chemistry Calculations (QCCs). QCC results were also used to model the experimental two-photon absorption cross-sectional spectrum by the Sum-Over-States (SOS) approach, revealing a dependence between the coupling of the ground state with the first excited state and the transition dipole moment between these states.

Indexed as

ChalconeChalconesAcetamidesCross-Sectional StudiesSpectrum AnalysisAcetamidesChalconeChalconesacetamide-chalconesdimethylamine groupSOS modeltwo and three-photon excited fluorescence emissiontwo-photon cross-section

Identifiers

PMID36838561
PMCPMC9963839

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.