ArticleMaterials (Basel, Switzerland)2023
The Role of Diisocyanate Structure to Modify Properties of Segmented Polyurethanes.
Article in Materials (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
8 citing papers in PubMed, 40 citations in OpenAlex.
- Synthesis of Bio-Based Polyurethanes from Functionalized Sunflower Seed Oil.International journal of molecular sciences · 2025Article
- Structure-Property Relationship between Hard Segments of Shape Memory Polyurethane Copolymers and Interchain Hydrogen Bonds: A Comprehensive Theoretical Study.The journal of physical chemistry. B · 2025Article
- Tailored Thermoresponsive Polyurethane Hydrogels: Structure-Property Relationships for Injectable Biomedical Applications.Polymers · 2025Article
- Article
- Role of the Soft and Hard Segments Structure in Modifying the Performance of Acrylic Adhesives Modified by Polyurethane Macromonomers.ACS omega · 2024Article
- Evaluation of 2,3-butanediol derived from whey fermentation as an effective bio-based monomer for waterborne polyurethane dispersions.Frontiers in chemistry · 2024Article
- Article
- The Influence of Diisocyanate Structure on Thermal Stability of Thermoplastic Polyurethane Elastomers Based on Diphenylmethane-Derivative Chain Extender with Sulfur Atoms.Materials (Basel, Switzerland) · 2023Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
5 authors at 2 institutions in 1 country.
Funding
Abstract
Segmented thermoplastic polyurethanes (PU) were synthetized using a polycarbonatediol macrodiol as a flexible or soft segment with a molar mass of 2000 g/mol, and different diisocyanate molecules and 1,4-butanediol as a rigid or hard segment. The diisocyanate molecules employed are 3,3'-Dimethyl-4,4'-biphenyl diisocyanate (TODI), 4,4'-diphenylmethane diisocyanate (MDI), 4,4'-Methylenebis(phenyl isocyanate) 1-isocyanato-4-[(4-phenylisocyanate)methyl]benzene and 1-isocyanate-4-[(2-phenylisocyanate) methyl]benzene (ratio 1:1) (MDIi), isophorone diisocyanate (IPDI), and hexamethylene diisocyanate (HDI). The polyurethanes obtained reveal a wide variation of microphase separation degree that is correlated with mechanical properties. Different techniques, such as DSC, DMA, and FTIR, have been used to determine flexible-rigid segment phase behavior. Mechanical properties, such as tensile properties, Shore D hardness, and "compression set", have been determined. This work reveals that the structure of the hard segment is crucial to determine the degree of phase miscibility which affects the resulting mechanical properties, such as tensile properties, hardness, and "compression set".
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.