ReviewRSC advances2023
Ruthenium-catalyzed hydroarylation reactions as the strategy towards the synthesis of alkylated arenes and substituted alkenes.
Review in RSC advances, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- A decade of progress in transition metal-catalyzed sulfoxide reductions.Molecular diversity · 2026Review
- Ruthenium(II)-Catalyzed Alkenylation of Primary Arylacetamides: En Route Synthesis of Trisubstituted Alkenes.Chemistry, an Asian journal · 2026Article
- Variations in the Coordination Sphere of Ruthenacyclic Carbamoyl Complexes: Mapping Their Suitability for Direct Conjugation.ACS omega · 2025Article
- Research on transition metals for the multicomponent synthesis of benzo-fused γ-lactams.RSC advances · 2025Review
- Recent Advances in the Nickel-Catalyzed Alkylation of C-H Bonds.Molecules (Basel, Switzerland) · 2024Review
- Selective 1,2-Hydroarylation(Alkenylation) of gem-Difluoroalkenes to Access (-CFAngewandte Chemie (International ed. in English) · 2024Article
Corrections and comments
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Authors and funding
3 authors.
Funding
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Abstract
Metal-catalyzed hydroarylation reactions are always powerful tools in organic synthesis since they can form C-C or C-heteroatom bonds in an atom and step economic manner. Medicinally and biologically relevant scaffolds can be easily and efficiently synthesized using this strategy. By tuning the directing groups that are present on the arenes, regioselectivity can be induced to the C-H activation. Metals like cobalt, rhodium and ruthenium are well known as catalysts in this type of reaction. But due to their easy availability and efficiency, Ru catalysts are found to be more preferable for hydroarylation purposes. In this review, the Ru-catalyzed hydroarylation of alkenes and alkynes, intramolecular Ru-catalyzed hydroarylation of olefin tethered arenes, modifications in the catalytic system to improve the catalytic efficiency, and carboxylate-assisted Ru-catalyzed hydroarylation reactions are discussed in detail, covering literature from 2016 to 2022.
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Registered trials
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