Sulfur(iv) reagents for the SuFEx-based synthesis of substituted sulfamate esters.

Kathleen T Downey, Jia Yi Mo, Joey Lai, Brodie J Thomson, Glenn M Sammis

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Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it

0cells of the map it votes in

1citing papers in PubMed

1.0field-weighted citation impact, top 28% of its field

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 7 citations in OpenAlex.

Rapid peptide synthesis using a methylimidazolium sulfinyl fluoride salt.Communications chemistry · 2025
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 1 institution in 1 country.

Kathleen T DowneyDepartment of Chemistry, The University of British Columbia 2036 Main Mall Vancouver British Columbia V6T 1Z1 Canada gsammis@chem.ubc.ca.ORCID https://orcid.org/0000-0002-5870-185X

Jia Yi MoDepartment of Chemistry, The University of British Columbia 2036 Main Mall Vancouver British Columbia V6T 1Z1 Canada gsammis@chem.ubc.ca.

Joey LaiDepartment of Chemistry, The University of British Columbia 2036 Main Mall Vancouver British Columbia V6T 1Z1 Canada gsammis@chem.ubc.ca.ORCID https://orcid.org/0000-0001-6254-5004

Brodie J ThomsonDepartment of Chemistry, The University of British Columbia 2036 Main Mall Vancouver British Columbia V6T 1Z1 Canada gsammis@chem.ubc.ca.ORCID https://orcid.org/0000-0002-6959-4121

Glenn M SammisDepartment of Chemistry, The University of British Columbia 2036 Main Mall Vancouver British Columbia V6T 1Z1 Canada gsammis@chem.ubc.ca.ORCID https://orcid.org/0000-0002-8204-8571

University of British Columbia · CA

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Sulfur(vi) fluoride exchange chemistry has been reported to be effective at synthesizing valuable sulfur(vi) functionalities through sequential nucleophilic additions, yet oxygen-based nucleophiles are limited in this approach to phenolic derivatives. Herein, we report a new sulfur(iv) fluoride exchange strategy to access synthetically challenging substituted sulfamate esters from alkyl alcohols and amines. We also report the development of a non-gaseous, sulfur(iv) fluoride exchange reagent,

Identifiers

PMID36819869

DOI10.1039/d2sc05945b

PMCPMC9930924

OpenAlexW4317548841

What OpenQuestion holds

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LicenceCC BY

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.