Evidence map›Paper›PMID 36817007›Full record

ArticleACS measurement science au2023

Automated Measurement of Electrogenerated Redox Species Degradation Using Multiplexed Interdigitated Electrode Arrays.

Michael A Pence, Oliver Rodríguez, Nikita G Lukhanin, Charles M Schroeder, Joaquín Rodríguez-López

Open access · goldAbstract read
In one paragraph

Article in ACS measurement science au, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
2.2field-weighted citation impact, top 12% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed, 26 citations in OpenAlex.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 1 institution in 1 country.

Michael A PenceDepartment of Chemistry, University of Illinois at Urbana-Champaign, Urbana, Illinois61801, United States.ORCID https://orcid.org/0000-0001-5880-9812
Oliver RodríguezDepartment of Chemistry, University of Illinois at Urbana-Champaign, Urbana, Illinois61801, United States.ORCID https://orcid.org/0000-0003-2350-1214
Nikita G LukhaninDepartment of Chemistry, University of Illinois at Urbana-Champaign, Urbana, Illinois61801, United States.
Charles M SchroederDepartment of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois61801, United States.ORCID https://orcid.org/0000-0001-6023-2274
Joaquín Rodríguez-LópezDepartment of Chemistry, University of Illinois at Urbana-Champaign, Urbana, Illinois61801, United States.ORCID https://orcid.org/0000-0003-4346-4668
Argonne National Laboratory · US

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Characterizing the decomposition of electrogenerated species in solution is essential for applications involving electrosynthesis, homogeneous electrocatalysis, and energy storage with redox flow batteries. In this work, we present an automated, multiplexed, and highly robust platform for determining the rate constant of chemical reaction steps following electron transfer, known as the EC mechanism. We developed a generation-collection methodology based on microfabricated interdigitated electrode arrays (IDAs) with variable gap widths on a single device. Using a combination of finite-element simulations and statistical analysis of experimental data, our results show that the natural logarithm of collection efficiency is linear with respect to gap width, and this quantitative analysis is used to determine the decomposition rate constant of the electrogenerated species (

Identifiers

PMID36817007
PMCPMC9936799
OpenAlexW4307833989

What OpenQuestion holds

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LicenceCC BY-NC-ND
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.