Evidence map›Paper›PMID 36813263›Full record

ArticleThe Journal of organic chemistry2023

Experimental and Computational Investigation of Facial Selectivity Switching in Nickel-Diamine-Acetate-Catalyzed Michael Reactions.

Yoshihiro Sohtome, Shinsuke Komagawa, Ayako Nakamura, Daisuke Hashizume, Sylvain Lectard, Mai Akakabe, Yoshitaka Hamashima, Masanobu Uchiyama, Mikiko Sodeoka

Open access · hybridAbstract read
In one paragraph

Article in The Journal of organic chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
0.3field-weighted citation impact, top 50% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 2 citations in OpenAlex.

  1. Review
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 4 institutions in 1 country.

Yoshihiro SohtomeSynthetic Organic Chemistry Laboratory, RIKEN Cluster for Pioneering Research, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan.ORCID 0000-0002-9165-6720
Shinsuke KomagawaElements Chemistry Laboratory, RIKEN Cluster for Pioneering Research, Wako, Saitama 351-0198, Japan.ORCID 0000-0002-3699-7733
Ayako NakamuraSynthetic Organic Chemistry Laboratory, RIKEN Cluster for Pioneering Research, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan.ORCID 0000-0001-6236-991X
Daisuke HashizumeRIKEN Center for Emergent Matter Science, Wako, Saitama 351-0198, Japan.ORCID 0000-0001-7152-4408
Sylvain LectardSynthetic Organic Chemistry Laboratory, RIKEN Cluster for Pioneering Research, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan.
Mai AkakabeSynthetic Organic Chemistry Laboratory, RIKEN Cluster for Pioneering Research, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan.
Yoshitaka HamashimaSynthetic Organic Chemistry Laboratory, RIKEN Cluster for Pioneering Research, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan.ORCID 0000-0002-6509-8956
Masanobu UchiyamaRIKEN Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan.ORCID 0000-0001-6385-5944
Mikiko SodeokaSynthetic Organic Chemistry Laboratory, RIKEN Cluster for Pioneering Research, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan.ORCID 0000-0002-1344-364X
RIKEN Center for Sustainable Resource Science · JPRIKEN · JPPioneer (Japan) · JPRIKEN Center for Emergent Matter Science · JP

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Chiral Ni complexes have revolutionized both asymmetric acid-base and redox catalysis. However, the coordination isomerism of Ni complexes and their open-shell property still often hinder the elucidation of the origin of their observed stereoselectivity. Here, we report our experimental and computational investigations to clarify the mechanism of β-nitrostyrene facial selectivity switching in Ni(II)-diamine-(OAc)

Indexed as

DiaminesNickelAcetatesCarboxylic AcidsCatalysisLigandsOrganometallic CompoundsStyrenesAcetatesbeta-nitrostyreneCarboxylic AcidsDiaminesLigandsNickelnickel acetateOrganometallic CompoundsStyrenes

Identifiers

PMID36813263
PMCPMC10278084
OpenAlexW4321480111

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.