ArticleAngewandte Chemie (International ed. in English)2023
Ionothermal Synthesis of Metal-Organic Frameworks Using Low-Melting Metal Salt Precursors.
Article in Angewandte Chemie (International ed. in English), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Hybrid Modification Strategies of Metal-Organic Frameworks: A Review on Structural Design and Environmental Applications.ChemistryOpen · 2026Review
- Recent Advances in Antitumor Nanomedicine Based on Covalent Organic Frameworks.International journal of nanomedicine · 2026Review
- Electrochemical detection of atrazine using a zinc methylimidazolate framework with molecular docking insights.Scientific reports · 2025Article
- High-concentration aqueous synthesis of salicylate-based metal-organic frameworks.Journal of materials chemistry. A · 2025Article
- Mesoporous Potassium-Based Metal-Organic Framework as a Drug Carrier.ACS central science · 2025Article
- Solvent-free construction of Cr(iii)-sulfonate coordination polymers.Chemical science · 2025Article
- Controlled Growth and Interconversion of Photoluminescent Metal-Organic Frameworks Under High-Concentration Conditions.Chemistry of materials : a publication of the American Chemical Society · 2025Article
- Validation and Mechanistic Studies of the Headspace Effect in MOF Synthesis.Angewandte Chemie (International ed. in English) · 2025Article
- Cobalt(III) Halide Metal-Organic Frameworks Drive Catalytic Halogen Exchange.Journal of the American Chemical Society · 2024Article
- Simplifying the Synthesis of Metal-Organic Frameworks.Accounts of materials research · 2023Article
- MOFganic Chemistry: Challenges and Opportunities for Metal-Organic Frameworks in Synthetic Organic Chemistry.Chemistry of materials : a publication of the American Chemical Society · 2023Article
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Authors and funding
6 authors.
Funding
Abstract
Metal-organic frameworks (MOFs) are porous, crystalline materials constructed from organic linkers and inorganic nodes with myriad potential applications in chemical separations, catalysis, and drug delivery. A major barrier to the application of MOFs is their poor scalability, as most frameworks are prepared under highly dilute solvothermal conditions using toxic organic solvents. Herein, we demonstrate that combining a range of linkers with low-melting metal halide (hydrate) salts leads directly to high-quality MOFs without added solvent. Frameworks prepared under these ionothermal conditions possess porosities comparable to those prepared under traditional solvothermal conditions. In addition, we report the ionothermal syntheses of two frameworks that cannot be prepared directly under solvothermal conditions. Overall, the user-friendly method reported herein should be broadly applicable to the discovery and synthesis of stable metal-organic materials.
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