ArticleChemical science2023
Regioselectivity of concerted proton-electron transfer at the surface of a polyoxovanadate cluster.
Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Evidence for Site-Specific Tunneling in H Atom Uptake at the Surface of Polyoxovanadate-Alkoxides.JACS Au · 2026Article
- Redox-State-Driven Site Selectivity and Kinetic Gating in Polyoxovanadate Methylation.Inorganic chemistry · 2026Article
- Multisite Proton-Coupled Electron Transfer at a Keggin-Type Polyoxotungstate.Journal of the American Chemical Society · 2026Article
- Review
- The crystal structure of a spherical vanadium complex encapsulating a nitrate anion.Acta crystallographica. Section E, Crystallographic communications · 2025Article
- Vanadium Substitution Dictates H Atom Uptake at Lindqvist-type Polyoxotungstates.Inorganic chemistry · 2024Article
- Selective Hydrogenation of Azobenzene to Hydrazobenzene via Proton-Coupled Electron Transfer from a Polyoxotungstate Cluster.JACS Au · 2024Article
- Heterometal Dopant Changes the Mechanism of Proton-Coupled Electron Transfer at the Polyoxovanadate-Alkoxide Surface.Journal of the American Chemical Society · 2024Article
- Manipulating Ligand Density at the Surface of Polyoxovanadate-Alkoxide Clusters.Inorganic chemistry · 2023Article
- Vertex Differentiation Strategy for Tuning the Physical Properties ofInorganic chemistry · 2023Article
- Proton-Coupled Electron Transfer at the Surface of Polyoxovanadate-Alkoxide Clusters.Accounts of chemical research · 2023Article
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Proton-coupled electron transfer (PCET) is an important process in the activation and reactivity of metal oxide surfaces. In this work, we study the electronic structure of a reduced polyoxovanadate-alkoxide cluster bearing a single bridging oxide moiety. The structural and electronic implications of the incorporation of bridging oxide sites are revealed, most notably resulting in the quenching of cluster-wide electron delocalization in the most reduced state of the molecule. We correlate this attribute to a change in regioselectivity of PCET to the cluster surface (
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Registered trials
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