ArticleMaterials and structures2023
Speciation of iron(II/III) at the iron-cement interface: a review.
Article in Materials and structures, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed, 27 citations in OpenAlex.
- Rethinking concrete durability for low-carbon concretes through climate-informed corrosion modelling.Nature communications · 2026Article
- Premature Failure of Galvanized Fire Sprinkler Pipes in Coastal Conditions: Evidence of Sequential Atmospheric and Aqueous Corrosion.Materials (Basel, Switzerland) · 2026Article
- Evaluation of Cement Composites with Heavy Metal-Contaminated Recycled Aggregate: Toward Sustainable Utilization.Materials (Basel, Switzerland) · 2025Article
- Precipitation of corrosion products in macroscopic voids at the steel-concrete interface: observations, mechanisms and research needs.Materials and structures · 2025Article
- RAAC panels can suddenly collapse before any warning of corrosion-induced surface cracking.Npj Materials degradation · 2025Article
- Microscale chemical imaging to characterize and quantify corrosion processes at the metal-electrolyte interface.Npj Materials degradation · 2024Article
- Transformation of 2-Line Ferrihydrite to Goethite at Alkaline pH.Environmental science & technology · 2023Article
- Interactions between C-steel and blended cement in concrete under radwaste repository conditions at 80 °C.Scientific reports · 2023Article
Corrections and comments
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Authors and funding
5 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Steel is used as reinforcement in construction materials and it is also an important component of cement-stabilized waste materials to be disposed of in deep geological repositories for radioactive waste. Steel corrosion releases dissolved Fe(II/III) species that can form corrosion products on the steel surface or interact with cementitious materials at the iron-cement interface. The thermodynamically stable Fe species in the given conditions may diffuse further into the adjacent, porous cement matrix and react with individual cement phases. Thus, the retention of Fe(II/III) by the hydrate assemblage of cement paste is an important process affecting the diffusive transport of the aqueous species into the cementitious materials. The diffusion of aqueous Fe(II/III) species from the steel surface into the adjacent cementitious material coupled with the kinetically controlled formation of iron corrosion products, such as by Fe(II) oxidation, decisively determines the extension of the corrosion front. This review summarises the state-of-the art knowledge on the interaction of ferrous and ferric iron with cement phases based on a literature survey and provides new insights and proper perspectives for future study on interaction systems of iron and cement.
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