Evidence map›Paper›PMID 36770519›Full record

ArticleNanomaterials (Basel, Switzerland)2023

A Porphyrin-Based Covalent Organic Framework as Metal-Free Visible-LED-Light Photocatalyst for One-Pot Tandem Benzyl Alcohol Oxidation/Knoevenagel Condensation.

Sara Oudi, Ali Reza Oveisi, Saba Daliran, Mostafa Khajeh, Amarajothi Dhakshinamoorthy, Hermenegildo García

Abstract read
In one paragraph

Article in Nanomaterials (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Probing Defects in Covalent Organic Frameworks.ACS applied materials & interfaces · 2024
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Sara OudiDepartment of Chemistry, Faculty of Sciences, University of Zabol, Zabol P.O. Box 98615-538, Iran.
Ali Reza OveisiDepartment of Chemistry, Faculty of Sciences, University of Zabol, Zabol P.O. Box 98615-538, Iran.ORCID 0000-0002-0075-211X
Saba DaliranDepartment of Chemistry, Faculty of Sciences, University of Zabol, Zabol P.O. Box 98615-538, Iran.
Mostafa KhajehDepartment of Chemistry, Faculty of Sciences, University of Zabol, Zabol P.O. Box 98615-538, Iran.ORCID 0000-0002-7097-2898
Amarajothi DhakshinamoorthyDepartamento de Quimica, Universitat Politècnica de València, Av. De los Naranjos s/n, 46022 Valencia, Spain.ORCID 0000-0003-0991-6608
Hermenegildo GarcíaInstituto Universitario de Tecnología Química, Consejo Superior de Investigaciones Científicas-Universitat Politecnica de Valencia, Av. De los Naranjos s/n, 46022 Valencia, Spain.ORCID 0000-0002-9664-493X

Funding

Zabol University UOZ-GR-8175 and IR-UOZ-GR-9381
6 · The paper itself

Abstract

A porphyrin-based covalent organic framework (COF), namely Porph-UOZ-COF (UOZ stands for the University of Zabol), has been designed and prepared via the condensation reaction of 5,10,15,20-tetrakis-(3,4-dihydroxyphenyl)porphyrin (DHPP) with 1,4-benzenediboronic acid (DBBA), under the solvothermal condition. The solid was characterized by spectroscopic, microscopic, and powder X-ray diffraction techniques. The resultant multifunctional COF revealed an outstanding performance in catalyzing a one-pot tandem selective benzylic C-H photooxygenation/Knoevenagel condensation reaction in the absence of additives or metals under visible-LED-light irradiation. Notably, the catalytic activity of the COF was superior to individual organic counterparts and the COF was both stable and reusable for four consecutive runs. The present approach illustrates the potential of COFs as promising metal-free (photo) catalysts for the development of tandem reactions.

Indexed as

boronic ester linkagescarbon–carbon coupling reactioncascade reactioncovalent organic frameworkmultifunctional catalystphotooxidationporous materialsporphyrin

Identifiers

PMID36770519
PMCPMC9920377

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.