Spent Coffee as a Composite Filler for Wastewater Treatment.

Currently composites play an important role in all aspects of engineering and technology, with constantly growing applications. Recently, more attention was focused on natural fillers due to their suitability as reinforcement materials in thermo-plastic matrices which improve the mechanical properties of these polymers. Biofillers are used due to their low cost, high strength rigidity, non-toxicity, biodegradability, and availability. Currently, spent coffee grounds (SCG) are attracting more attention as a natural filler since high amounts of SCG are generated every day (food waste of coffee processing). This study allowed us to determine the long-term effect of activated sludge microorganisms with known technical and technological parameters on the mechanical properties of composites with spent coffee grounds filler. The fittings consisted of high-density poly-ethylene (PE-HD), which was used as the matrix, and a filler based on spent coffee grounds (SCG), which was used as a modifier. It was established that the composition of the composite and its residence time in the bioreactor directly influenced the contact angle value. The shift of the contact angle value is associated with the formation of the biofilm on the tested materials. An increase in the contact angle was observed in the case of all samples tested in the bioreactor, with the lowest values equal to approx. 76.4° for sample A (PE-HD) and higher values of approx. 90° for the remaining composite samples with a coffee grounds filler. The research confirmed that the increased ratio of coffee grounds in the composite results in the increased diversity and abundance of microorganisms. The highest number and the greatest diversity of microorganisms were observed in the case of the composite with 40% coffee grounds after more than a year of exposure in the bioreactor, while the composite with 30% SCG was second.