ArticleJournal of the American Chemical Society2023
Optical Activity and Spin Polarization: The Surface Effect.
Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
12 citing papers in PubMed, 38 citations in OpenAlex.
- Chiral-Induced Spin Selectivity Effect in a 1 nm Thin 1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate Self-Assembled Monolayer on Nickel Oxide.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Photocatalytic COAdvanced materials (Deerfield Beach, Fla.) · 2026Article
- Oxygen-Controlled Assembly of Chiral [7]-Helicene on ZnO Surfaces.Langmuir : the ACS journal of surfaces and colloids · 2026Article
- Close-Shell and Biradical Enantiomers for Probing the Chiral-Induced Spin Selectivity Effect.The journal of physical chemistry letters · 2026Article
- Stepwise π-extension of double [5]helicene diimides to planar nanographene diimides.Communications chemistry · 2025Article
- Probing the Roles of Temperature and Cooperative Effects in Chirality-Induced Spin Selectivity: Photoelectron Spin Polarization in Helical Tetrapyrroles.The journal of physical chemistry letters · 2024Article
- Asymmetric Polarization in a Rough Multilayer: Towards the Discrimination of Enantiomer Pairs.Nanomaterials (Basel, Switzerland) · 2024Article
- Helitwistacenes-Combining Lateral and Longitudinal Helicity Results in Solvent-Induced Inversion of Circularly Polarized Light.Angewandte Chemie (International ed. in English) · 2024Article
- Mechanism for Electrostatically Generated Magnetoresistance in Chiral Systems without Spin-Dependent Transport.ACS nano · 2024Review
- Highly Conductive Topologically Chiral Molecular Knots as Efficient Spin Filters.Journal of the American Chemical Society · 2023Article
- Detection of a Chirality-Induced Spin Selective Quantum Capacitance in α-Helical Peptides.Nano letters · 2023Article
- Effect of Chalcogenophenes on Chiroptical Activity of Twisted Tetracenes: Computational Analysis, Synthesis and Crystal Structure Thereof.Molecules (Basel, Switzerland) · 2023Article
Corrections and comments
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Authors and funding
12 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Chirality ('handedness') is a property that underlies a broad variety of phenomena in nature. Chiral molecules appear in two forms, and each is a mirror image of the other, the two enantiomers. The chirality of molecules is associated with their optical activity, and circular dichroism is commonly applied to identify the handedness of chiral molecules. Recently, the chiral induced spin selectivity (CISS) effect was established, according to which transfer of electrons within chiral molecules depends on the electron's spin. Which spin is preferred depends on the handedness of the chiral molecule and the direction of motion of the electron. Several experiments in the past indicated that there may be a relation between the optical activity of the molecules and their spin selectivity. Here, we show that for a molecule containing several stereogenic axes, when adsorbed on a metal substrate, the peaks in the CD spectra have the same signs for the two enantiomers. This is not the case when the molecules are adsorbed on a nonmetallic substrate or dissolved in solution. Quantum chemical simulations are able to explain the change in the CD spectra upon adsorption of the molecules on conductive and nonconductive surfaces. Surprisingly, the CISS properties are similar for the two enantiomers when adsorbed on the metal substrate, while when the molecules are adsorbed on nonmetallic surface, the preferred spin depends on the molecule handedness. This correlation between the optical activity and the CISS effect indicates that the CISS effect relates to the global polarizability of the molecule.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.