ArticleScience advances2023
One-dimensional alignment of defects in a flexible metal-organic framework.
Article in Science advances, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
6 citing papers in PubMed.
- Applications and future development of solid-state nuclear magnetic resonance for investigating metal-organic frameworks.Magnetic resonance letters · 2027Review
- Development and comparative investigation of structural and functional properties of Ni-based metal-organic frameworks designed for photocatalytic hydrogen production.RSC advances · 2026Article
- Defect-Guided Assembly of Aperiodic and Flexible Metal-Organic Frameworks From Pre-Formed Cages.Angewandte Chemie (International ed. in English) · 2026Article
- Water-generated dangling linkers in a metal-organic framework.Nature communications · 2026Article
- Targeted Selenite Adsorption Using Defective Fe-BTC: Effective in Acidic and Alkaline Conditions.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Effect of modulator ligands on the growth of CoChemical science · 2023Article
Corrections and comments
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Authors and funding
14 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Crystalline materials are often considered to have rigid periodic lattices, while soft materials are associated with flexibility and nonperiodicity. The continuous evolution of metal-organic frameworks (MOFs) has erased the boundaries between these two distinct conceptions. Flexibility, disorder, and defects have been found to be abundant in MOF materials with imperfect crystallinity, and their intricate interplay is poorly understood because of the limited strategies for characterizing disordered structures. Here, we apply advanced nuclear magnetic resonance spectroscopy to elucidate the mesoscale structures in a defective MOF with a semicrystalline lattice. We show that engineered defects can tune the degree of lattice flexibility by combining both ordered and disordered compartments. The one-dimensional alignment of correlated defects is the key for the reversible topological transition. The unique matrix is featured with both rigid framework of nanoporosity and flexible linkage of high swellability.
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Registered trials
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