Evidence map›Paper›PMID 36756407›Full record

ArticleRSC advances2023

Boron-catalysed transition-metal-free arylation and alkenylation of allylic alcohols with boronic acids.

Sixian Lu, Xingyu Chen, Xiaoqiang Chang, Shuaichen Zhang, Dong Zhang, Yifan Zhao, Lan Yang, Yue Ma, Peng Sun

Open access · goldAbstract read
In one paragraph

Article in RSC advances, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.7field-weighted citation impact, top 35% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 5 citations in OpenAlex.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 2 institutions in 1 country.

Sixian LuInstitute of Chinese Materia Medica and Artemisinin Research Center, Academy of Chinese Medical Sciences Beijing 100700 China yma@icmm.ac.cn psun@icmm.ac.cn.
Xingyu ChenSchool of Pharmacy, Chengdu University Chengdu Sichuan 610106 China.
Xiaoqiang ChangInstitute of Chinese Materia Medica and Artemisinin Research Center, Academy of Chinese Medical Sciences Beijing 100700 China yma@icmm.ac.cn psun@icmm.ac.cn.
Shuaichen ZhangInstitute of Chinese Materia Medica and Artemisinin Research Center, Academy of Chinese Medical Sciences Beijing 100700 China yma@icmm.ac.cn psun@icmm.ac.cn.
Dong ZhangInstitute of Chinese Materia Medica and Artemisinin Research Center, Academy of Chinese Medical Sciences Beijing 100700 China yma@icmm.ac.cn psun@icmm.ac.cn.
Yifan ZhaoInstitute of Chinese Materia Medica and Artemisinin Research Center, Academy of Chinese Medical Sciences Beijing 100700 China yma@icmm.ac.cn psun@icmm.ac.cn.
Lan YangInstitute of Chinese Materia Medica and Artemisinin Research Center, Academy of Chinese Medical Sciences Beijing 100700 China yma@icmm.ac.cn psun@icmm.ac.cn.
Yue MaInstitute of Chinese Materia Medica and Artemisinin Research Center, Academy of Chinese Medical Sciences Beijing 100700 China yma@icmm.ac.cn psun@icmm.ac.cn.
Peng SunInstitute of Chinese Materia Medica and Artemisinin Research Center, Academy of Chinese Medical Sciences Beijing 100700 China yma@icmm.ac.cn psun@icmm.ac.cn.ORCID https://orcid.org/0000-0003-0348-5405
Chinese Academy of Medical Sciences & Peking Union Medical College · CNChengdu University · CN

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The development of efficient catalytic reactions with excellent atom and step economy employing sustainable catalysts is highly sought-after in chemical synthesis to reduce the negative effects on the environment. The most commonly-used strategy to construct allylic compounds relies on the transition-metal-catalysed nucleophilic substitution reaction of allylic alcohol derivatives. These syntheses exhibit good yield and selectivity, albeit at the expense of toxic and expensive catalysts and extra steps. In this paper, we report a transition-metal-free arylation and alkenylation reaction between unprotected allylic alcohols and boronic acids. The reactions were performed with B(C

Identifiers

PMID36756407
PMCPMC9869934
OpenAlexW4319656686

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.