Evidence map›Paper›PMID 36755710›Full record

ArticleChemical science2023

Statistical copolymer metal organic nanotubes.

Jacob A Barrett, Nathan D Rosenmann, Karthikeyan Gnanasekaran, Xian B Carroll, Nathan C Gianneschi, David M Jenkins

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Jacob A BarrettDepartment of Chemistry, University of Tennessee Knoxville Tennessee 37996 USA jenkins@ion.chem.utk.edu.
Nathan D RosenmannDepartments of Chemistry, Materials Science & Engineering, Biomedical Engineering, Pharmacology, International Institute for Nanotechnology, Simpson-Querrey Institute, Chemistry of Life Processes Institute, Lurie Cancer Center, Northwestern University Evanston Illinois 60208 USA nathan.gianneschi@northwestern.edu.
Karthikeyan GnanasekaranDepartments of Chemistry, Materials Science & Engineering, Biomedical Engineering, Pharmacology, International Institute for Nanotechnology, Simpson-Querrey Institute, Chemistry of Life Processes Institute, Lurie Cancer Center, Northwestern University Evanston Illinois 60208 USA nathan.gianneschi@northwestern.edu.ORCID https://orcid.org/0000-0001-6635-0888
Xian B CarrollDepartment of Chemistry, University of Tennessee Knoxville Tennessee 37996 USA jenkins@ion.chem.utk.edu.
Nathan C GianneschiDepartments of Chemistry, Materials Science & Engineering, Biomedical Engineering, Pharmacology, International Institute for Nanotechnology, Simpson-Querrey Institute, Chemistry of Life Processes Institute, Lurie Cancer Center, Northwestern University Evanston Illinois 60208 USA nathan.gianneschi@northwestern.edu.ORCID https://orcid.org/0000-0001-9945-5475
David M JenkinsDepartment of Chemistry, University of Tennessee Knoxville Tennessee 37996 USA jenkins@ion.chem.utk.edu.ORCID https://orcid.org/0000-0003-2683-9157

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Metal-organic nanotubes (MONTs) are 1-dimensional crystalline porous materials that are formed from ligands and metals in a manner identical to more typical 3-dimensional metal-organic frameworks (MOFs). MONTs form anisotropically in one dimension making them excellent candidates for linker engineering for control of chemical composition and spacing. A novel series of MONTs was synthesized utilizing a mixture of 1,2,4-ditriazole ligands containing both a fully protonated aryl moiety and its tetrafluorinated analog in ratios of, 0 : 1, 1 : 4, 1 : 1, 4 : 1, and 1 : 0, respectively. All MONTs were characterized by both bulk and nanoscale measurements, including SCXRD, PXRD, ssNMR and TEM, to determine the resulting co-polymer architecture (alternating, block, or statistical) and the ligand ratios in the solid materials. All characterization methods point towards statistical copolymerization of the materials in a manner analogous to 3D MOFs, all of which notably could be achieved without destructive analytical methods.

Identifiers

PMID36755710
PMCPMC9890963

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.