ArticleScience advances2023
A van der Waals heterojunction strategy to fabricate layer-by-layer single-molecule switch.
Article in Science advances, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Determinants of electron transport at asymmetric metal/molecule/metal contacts.Nature communications · 2026Article
- A graphene-coated AFM probe for durable and reproducible nanoscale electronic measurements.Nanoscale advances · 2026Article
- Intramolecular London Dispersion Interactions in Single-Molecule Junctions.Journal of the American Chemical Society · 2024Article
- A high-performance molecular switch fabricated by the two-dimensional van der Waals heterojunction.National science review · 2023Article
- Atomically well-defined nitrogen doping for cross-plane transport through graphene heterojunctions.Chemical science · 2023Article
Corrections and comments
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Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Single-molecule electronics offer a unique strategy for the miniaturization of electronic devices. However, the existing experiments are limited to the conventional molecular junctions, where a molecule anchors to the electrode pair with linkers. With such a rod-like configuration, the minimum size of the device is defined by the length of the molecule. Here, by incorporating a single molecule with two single-layer graphene electrodes, we fabricated layer-by-layer single-molecule heterojunctions called single-molecule two-dimensional van der Waals heterojunctions (M-2D-vdWHs), of which the sizes are defined by the thickness of the molecule. We controlled the conformation of the M-2D-vdWHs and the cross-plane charge transport through them with the applied electric field and established that they can serve as reversible switches. Our results demonstrate that the M-2D-vdWHs, as stacked from single-layer 2D materials and a single molecule, can respond to electric field stimulus, which promises a diverse class of single-molecule devices with unprecedented size.
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Registered trials
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