Evidence map›Paper›PMID 36741525›Full record

ArticleChemical science2023

Supramolecular multi-electron redox photosensitisers comprising a ring-shaped Re(i) tetranuclear complex and a polyoxometalate.

Maria Takahashi, Tsuyoshi Asatani, Tatsuki Morimoto, Yoshinobu Kamakura, Kotaro Fujii, Masatomo Yashima, Naoki Hosokawa, Yusuke Tamaki, Osamu Ishitani

Open access · diamondAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
0.9field-weighted citation impact, top 30% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed, 14 citations in OpenAlex.

  1. Review
  2. Review
  3. Article
  4. Photochemical reduction of CORSC advances · 2023
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors at 3 institutions in 1 country.

Maria TakahashiDepartment of Chemistry, School of Science, Tokyo Institute of Technology O-okayama 2-12-1-NE-1 Meguro-ku Tokyo 152-8550 Japan ishitani@chem.titech.ac.jp.
Tsuyoshi AsataniDepartment of Chemistry, School of Science, Tokyo Institute of Technology O-okayama 2-12-1-NE-1 Meguro-ku Tokyo 152-8550 Japan ishitani@chem.titech.ac.jp.
Tatsuki MorimotoSchool of Engineering, Tokyo University of Technology 1404-1 Katakura Hachioji Tokyo 192-0982 Japan.
Yoshinobu KamakuraDepartment of Chemistry, School of Science, Tokyo Institute of Technology O-okayama 2-12-1-NE-1 Meguro-ku Tokyo 152-8550 Japan ishitani@chem.titech.ac.jp.ORCID https://orcid.org/0000-0001-5189-7119
Kotaro FujiiDepartment of Chemistry, School of Science, Tokyo Institute of Technology O-okayama 2-12-1-NE-1 Meguro-ku Tokyo 152-8550 Japan ishitani@chem.titech.ac.jp.ORCID https://orcid.org/0000-0003-3309-9118
Masatomo YashimaDepartment of Chemistry, School of Science, Tokyo Institute of Technology O-okayama 2-12-1-NE-1 Meguro-ku Tokyo 152-8550 Japan ishitani@chem.titech.ac.jp.ORCID https://orcid.org/0000-0001-5406-9183
Naoki HosokawaDepartment of Chemistry, School of Science, Tokyo Institute of Technology O-okayama 2-12-1-NE-1 Meguro-ku Tokyo 152-8550 Japan ishitani@chem.titech.ac.jp.
Yusuke TamakiDepartment of Chemistry, School of Science, Tokyo Institute of Technology O-okayama 2-12-1-NE-1 Meguro-ku Tokyo 152-8550 Japan ishitani@chem.titech.ac.jp.
Osamu IshitaniDepartment of Chemistry, School of Science, Tokyo Institute of Technology O-okayama 2-12-1-NE-1 Meguro-ku Tokyo 152-8550 Japan ishitani@chem.titech.ac.jp.ORCID https://orcid.org/0000-0001-9557-7854
Tokyo Institute of Technology · JPHiroshima University · JPTokyo University of Technology · JP

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Redox photosensitisers (PSs) play essential roles in various photocatalytic reactions. Herein, we synthesised new redox PSs of 1 : 1 supramolecules that comprise a ring-shaped Re(i) tetranuclear complex with 4+ charges and a Keggin-type heteropolyoxometalate with 4- charges. These PSs photochemically accumulate multi-electrons in one molecule (three or four electrons) in the presence of an electron donor and can supply electrons with different reduction potentials. PSs were successfully applied in the photocatalytic reduction of CO

Identifiers

PMID36741525
PMCPMC9848162
OpenAlexW4313042484

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.