Investigation of enhanced Am selectivity for Eu in solvent extraction using a BTPhen ligand substituted with halogen.

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Article in RSC advances, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it

0cells of the map it votes in

1citing papers in PubMed

0.1field-weighted citation impact, top 64% of its field

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 1 citations in OpenAlex.

Theoretical study on the bonding properties and separation performance of ligands with symmetric and asymmetric side rings and ortho-phenanthroline skeletons for Am(III)/Eu(III).Journal of molecular modeling · 2025
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors at 1 institution in 1 country.

Yuto FukasawaBasic Chemistry Program, Graduate School of Advanced Science and Engineering, Hiroshima University 1-3-1 Kagamiyama Higashi-Hiroshima Hiroshima 739-8526 Japan snaka@hiroshima-u.ac.jp.

Satoru NakashimaBasic Chemistry Program, Graduate School of Advanced Science and Engineering, Hiroshima University 1-3-1 Kagamiyama Higashi-Hiroshima Hiroshima 739-8526 Japan snaka@hiroshima-u.ac.jp.ORCID https://orcid.org/0000-0001-6870-802X

Hiroshima University · JP

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The effect of bromine (Br) on the separation of Am/Eu using BTPhen was investigated using DFT calculations. The simulated results agreed well with the reported experimental result of Br substitution. It is concluded that the contribution of the d orbital becomes less important by increasing the number of Br atoms, that is, the relative contribution of the f orbital becomes important. The Am f orbital contributed to both bonding and antibonding interactions with the ligand, whereas the Eu f orbital contributed to the antibonding interaction with the ligand. To study the halogen effect systematically, we introduced a series of new halogen atoms (chlorine, fluorine, iodine) into BTPhen. When the electronegativity of the halogen atom increases, the Δ

Identifiers

PMID36741186

DOI10.1039/d2ra05515e

PMCPMC9841579

OpenAlexW4319293847

What OpenQuestion holds

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LicenceCC BY

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.