ArticleNature communications2023
Topological dual and extended relations between networks of clathrate hydrates and Frank-Kasper phases.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Rapid conversion of amino acid modified-ice to methane hydrate for sustainable energy storage.Nature communications · 2025Article
- Discovery of the final primitive Frank-Kasper phase of clathrate hydrates.Science advances · 2024Article
- Article
- Self-assembled soft alloy with Frank-Kasper phases beyond metals.Nature materials · 2024Article
- Atomistic-geometry inspired structure-composition-property relations of hydrogen sII hydrates.Scientific reports · 2023Article
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Authors and funding
3 authors.
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No grant is acknowledged in the PubMed record.
Abstract
Clathrate hydrates are a class of ordered structures that are stabilized via the delicate balance of hydrophobic interactions between water and guest molecules, of which the space-filling network of hydrogen-bonded (H-bonded) water molecules are closely related to tetrahedrally close-packed structures, known as Frank-Kasper (FK) phases. Here we report an alternative way to understand the intricate structures of clathrate hydrates, which unveils the diverse crystalline H-bonded networks that can be generated via assembly of one common building block. In addition to the intrinsic relations and pathways linking these crystals, we further illustrate the rich structural possibilities of clathrate hydrates. Given that the topological dual relations between networks of clathrate hydrates and tetrahedral close-packed structures, the descriptors presented for clathrate hydrates can be directly extended to other ordered materials for a more thorough understanding of their nucleation, phases transition, and co-existence mechanisms.
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