ArticleNature communications2023
Orientated crystallization of FA-based perovskite via hydrogen-bonded polymer network for efficient and stable solar cells.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 34 papers.
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Who cites it
34 citing papers in PubMed, 341 citations in OpenAlex.
- Self-Healing Ionogel Dual-Network Enables Synergistic Defect Passivation and Strain Relief for High-Efficiency Robust Perovskite Photovoltaics.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Regulating lattice evolution via an ordered two-dimensional intermediate phase for resilient perovskite solar cells.Nature communications · 2026Article
- Modulation of Crystal Plane Growth for Efficient and Stable Perovskite Solar Cells.Angewandte Chemie (International ed. in English) · 2026Article
- Direct Nanocrystal Seeding Enables Buried Interface Passivation and Enhanced Crystallization for FAPbISmall (Weinheim an der Bergstrasse, Germany) · 2026Article
- Dual-Functional Ionic Liquid Additive Enables High-Performance Perovskite Solar Cells by Suppressing Ion Migration and Passivating Defects.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Homogenizing Sn-Pb Distribution Through A-Site MA Cations for Efficient All-Perovskite Tandem Solar Cells.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Coherent transformation of metal halide perovskites.Nature communications · 2026Article
- Molecularly Confined Domains Enable Halide-Stable Wide-Bandgap Perovskites.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Crystallization Pathway Optimization and High-Index Facet Stabilization for Perovskite Photovoltaics.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Polymer-templated mesoscale assembly directs synthesis of centimetre-scale perovskite single crystals.Nature communications · 2026Article
- Molecular confinement for enhanced interfacial contact and performance in inverted perovskite solar cells.Nature communications · 2026Article
- Enhancing Wide-Bandgap Triple-Halide Perovskites for Tandem Solar Cells by 0.5% Formate and Zn(II) Doping.Molecules (Basel, Switzerland) · 2026Article
- One-Step Formation of 2D/3D Perovskite Heterojunction via Ligand Intercalation and Facet Engineering for Efficient Perovskite Solar Cells.Nano-micro letters · 2026Article
- Polarize the Solvent to Regulate the Intermediate Phase and Dynamic Crystallization of Perovskite Films.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- A self-assembled molecule directs ordered α-FAPbINature communications · 2026Article
- Thermotropic liquid-assisted interface management enables efficient and stable perovskite solar cells and modules.Nature communications · 2026Article
- Ammonia Borane All-In-One Modification Strategy Enables High-Performance Perovskite Solar Cells.Nano-micro letters · 2026Article
- Oriented Crystallization of Perovskite Film via Fluorine-Containing Hyperbranched Polymer for Efficient and Stable Perovskite Solar Cells.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Tailoring Precursor-Solvent Coordination Controls the Crystallization Kinetics and Nuclei Growth for Phase Homogenization in Wide-Bandgap Perovskite Solar Cells.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- How crystallization additives govern halide perovskite grain growth.Nature communications · 2025Article
Corrections and comments
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Authors and funding
18 authors at 3 institutions in 1 country.
Funding
Abstract
Incorporating mixed ion is a frequently used strategy to stabilize black-phase formamidinum lead iodide perovskite for high-efficiency solar cells. However, these devices commonly suffer from photoinduced phase segregation and humidity instability. Herein, we find that the underlying reason is that the mixed halide perovskites generally fail to grow into homogenous and high-crystalline film, due to the multiple pathways of crystal nucleation originating from various intermediate phases in the film-forming process. Therefore, we design a multifunctional fluorinated additive, which restrains the complicated intermediate phases and promotes orientated crystallization of α-phase of perovskite. Furthermore, the additives in-situ polymerize during the perovskite film formation and form a hydrogen-bonded network to stabilize α-phase. Remarkably, the polymerized additives endow a strongly hydrophobic effect to the bare perovskite film against liquid water for 5 min. The unencapsulated devices achieve 24.10% efficiency and maintain >95% of the initial efficiency for 1000 h under continuous sunlight soaking and for 2000 h at air ambient of ~50% humid, respectively.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.