ArticleNature communications2023
Achiral organoiodine-functionalized helical polyisocyanides for multiple asymmetric dearomative oxidations.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
9 citing papers in PubMed, 44 citations in OpenAlex.
- Chiral Tetraazacalix-Triazine Derivatives as Organocatalysts for Asymmetric Direct Aldol Reactions: Synthesis and Enantioselective Evaluation.Chirality · 2026Article
- Achiral benzoic acid appended helical polymers for the copper-catalyzed asymmetric Diels-Alder reaction and Michael addition with excellent enantioselectivity and recyclability.Chemical science · 2026Article
- Harnessing Poly(9,9-dialkylfluorene-alt-benzothiadiazole) for Circularly Polarized Electroluminescence: Advances and Perspectives.Materials (Basel, Switzerland) · 2026Review
- Helix Regulation of Poly(phenylacetylene)s through the Interplay between Enantiomeric Excess and Temperature-Triggered Pendant Isomerization.Precision chemistry · 2025Article
- Chiroptical isomerization in chiral covalent organic frameworks with identical mesoscopic helicity.Nature communications · 2025Article
- Thermal Activation of Asymmetry Amplification Effects in Helical Polymer-Metal Complexes.Angewandte Chemie (International ed. in English) · 2025Article
- Helical polyisocyanide-based macroporous organic catalysts for asymmetric Michael addition with high efficiency and stereoselectivity.Chemical science · 2024Article
- Switchable supramolecular helices for asymmetric stereodivergent catalysis.Nature communications · 2024Article
- Thermo-responsive chiral micelles as recyclable organocatalyst for asymmetric Rauhut-Currier reaction in water.Nature communications · 2023Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
7 authors at 2 institutions in 1 country.
Funding
Abstract
Immobilizing organocatalyst onto helical polymers not only facilitates the catalyst recycling from homogeneous reactions, but also boosts enantioselectivity. In this work, achiral organoiodine-functionalized single left- and right-handed helical polyisocyanides were prepared from the same monomers, which catalyzed three asymmetric oxidations gave the desired products in high yields and excellent enantioselectivity. The enantiomeric excess of the target products was up to 95%. Remarkably, the enantioselectivity can be switched by reversing the helicity of the polymer backbone. The polymer catalysts can be facilely recovered and recycled in different asymmetric oxidations with maintained excellent activity and enantioselectivity.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.