Evidence map›Paper›PMID 36720708›Full record

ArticleAngewandte Chemie (International ed. in English)2023

A Bidentate Ligand Featuring Ditopic Lewis Acids in the Second Sphere for Selective Substrate Capture and Activation.

Daniel M Beagan, John J Kiernicki, Matthias Zeller, Nathaniel K Szymczak

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Gem-Diboronic Acids: A Motif for Anion Recognition in Competitive Media.Angewandte Chemie (International ed. in English) · 2025
    Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Daniel M BeaganDepartment of Chemistry, University of Michigan, 930 N. University, Ann Arbor, MI 48109, USA.
John J KiernickiDepartment of Chemistry, University of Michigan, 930 N. University, Ann Arbor, MI 48109, USA.
Matthias ZellerH.C. Brown Laboratory, Department of Chemistry, Purdue University, 560 Oval Dr., West Lafayette, IN 47907, USA.
Nathaniel K SzymczakDepartment of Chemistry, University of Michigan, 930 N. University, Ann Arbor, MI 48109, USA.ORCID http://orcid.org/0000-0002-1296-1445

Funding

The Role of Secondary Interactions Relevant to Biological Reductions of Small MoleculesR35GM136360 · NIGMS · UNIVERSITY OF MICHIGAN AT ANN ARBOR · PI Nathaniel Kolnik Szymczak · 2020 to 2026
$2.5M
Camille and Henry Dreyfus FoundationDivision of Chemistry 1625543National Institute of Health 1R35GM136360-01NIGMS NIH HHS R35 GM136360
6 · The paper itself

Abstract

We present a ligand platform featuring appended ditopic Lewis acids to facilitate capture/activation of diatomic substrates. We show that incorporation of two 9-borabicyclo[3.3.1]nonane (9-BBN) units on a single carbon tethered to a pyridine pyrazole scaffold maintains a set of unquenched nitrogen donors available to coordinate Fe

Indexed as

Chemoselective Anion BindingDitopic BoranesHydrazine FunctionalizationLewis AcidsSecondary Coordination Sphere

Identifiers

PMID36720708
PMCPMC10023486

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.