ArticleJournal of the American Chemical Society2023
Polarity Transduction Enables the Formal Electronically Mismatched Radical Addition to Alkenes.
Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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Who cites it
21 citing papers in PubMed, 49 citations in OpenAlex.
- Photocatalytic Radical Functionalization of Alkenylammonium Salts.Precision chemistry · 2026Article
- Deoxygenative Single-Carbon Atom Transfer: Accessing Strained Carbocycles From Alkenes and Aldehydes With Designer Dual-Functional Reagent.Angewandte Chemie (International ed. in English) · 2026Article
- Overriding the radical polarity matching principle: selective chlorohydroxylation of electron-deficient alkenes enabled by Ce photocatalysis.Chemical science · 2026Article
- Magnesium-Assisted Photoinduced Polarity-Mismatched Coupling: Access to Thioester-Decorated Oxindoles and Fused Heterocycles.ChemSusChem · 2026Article
- Anti-Markovnikov alkene hydroalkylation via iron photocatalysis.Nature catalysis · 2026Article
- Article
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- Microfluidic Photocatalytic Ring Expansion of Sulfonium Salts for the Synthesis of Cyclic Sulfides.ACS catalysis · 2025Article
- Enhancing Electron Donor-Acceptor Complex Photoactivation with a Stable Perylene Diimide Metal-Organic Framework.Journal of the American Chemical Society · 2025Article
- Bismuth-photocatalysed Heck-type coupling with alkyl and aryl electrophiles.Nature catalysis · 2025Article
- Metal-Catalyzed Hydrogen Atom Transfer (MHAT) Hydroalkylation with Electron-Deficient Alkynes.Organic letters · 2024Article
- Arylthianthrenium Salts for Triplet Energy Transfer Catalysis.Journal of the American Chemical Society · 2024Article
- Carbosulfonylation of Alkynes: A Direct Conversion of sp-C to spOrganic letters · 2024Article
- Shedding light on thermally-activated delayed fluorescence.Chemical science · 2024Review
- Alkene Thianthrenation Unlocks Diverse Cation Synthons: Recent Progress and New Opportunities.Angewandte Chemie (International ed. in English) · 2024Review
- Nucleophilic functionalization of thianthrenium salts under basic conditions.Beilstein journal of organic chemistry · 2024Article
- Iron-Catalyzed Enantioselective Multicomponent Cross-Couplings of α-Boryl Radicals.Organic letters · 2023Article
- Red-light-mediated Barton decarboxylation reaction and one-pot wavelength-selective transformations.Chemical science · 2023Article
- A Chemoselective Polarity-Mismatched Photocatalytic C(spAngewandte Chemie (International ed. in English) · 2023Article
- Oxetane Synthesis via Alcohol C-H Functionalization.Journal of the American Chemical Society · 2023Article
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The formation of carbon-carbon bonds via the intermolecular addition of alkyl radicals to alkenes is a cornerstone of organic chemistry and plays a central role in synthesis. However, unless specific electrophilic radicals are involved, polarity matching requirements restrict the alkene component to be electron deficient. This limits the scope of a fundamentally important carbon-carbon bond forming process that could otherwise be more universally applied. Herein, we introduce a
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.