Evidence map›Paper›PMID 36716284›Full record

ArticleInorganic chemistry2023

Adduct Ions as Diagnostic Probes of Metallosupramolecular Complexes Using Ion Mobility Mass Spectrometry.

Niklas Geue, Tom S Bennett, Lennart A I Ramakers, Grigore A Timco, Eric J L McInnes, Neil A Burton, P B Armentrout, Richard E P Winpenny, Perdita E Barran

Abstract read
In one paragraph

Article in Inorganic chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.

0numbers the graph read from it
0cells of the map it votes in
14citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

14 citing papers in PubMed.

  1. Article
  2. A Novel Heterometallic Ring {CrChemistry (Weinheim an der Bergstrasse, Germany) · 2026
    Article
  3. Article
  4. Self-Assembly, Rearrangement, and Disassembly of {CrAngewandte Chemie (International ed. in English) · 2025
    Article
  5. Article
  6. Hybrid Inorganic-Organic Rotaxanes and Related Compounds.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025
    Review
  7. Article
  8. Review
  9. Studying Cation Exchange in {CrChemistry (Weinheim an der Bergstrasse, Germany) · 2024
    Article
  10. Article
  11. Review
  12. Article
  13. Article
  14. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Niklas GeueMichael Barber Centre for Collaborative Mass Spectrometry, Manchester Institute of Biotechnology, Department of Chemistry, The University of Manchester, 131 Princess Street, Manchester M1 7DN, UK.ORCID 0000-0002-5216-8353
Tom S BennettDepartment of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, UK.
Lennart A I RamakersMichael Barber Centre for Collaborative Mass Spectrometry, Manchester Institute of Biotechnology, Department of Chemistry, The University of Manchester, 131 Princess Street, Manchester M1 7DN, UK.
Grigore A TimcoDepartment of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, UK.ORCID 0000-0003-0966-0315
Eric J L McInnesDepartment of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, UK.ORCID 0000-0002-4090-7040
Neil A BurtonDepartment of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, UK.
P B ArmentroutDepartment of Chemistry, University of Utah, Salt Lake City, Utah 84112, United States.ORCID 0000-0003-2953-6039
Richard E P WinpennyDepartment of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL, UK.ORCID 0000-0002-7101-3963
Perdita E BarranMichael Barber Centre for Collaborative Mass Spectrometry, Manchester Institute of Biotechnology, Department of Chemistry, The University of Manchester, 131 Princess Street, Manchester M1 7DN, UK.ORCID 0000-0002-7720-586X

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Following electrospray ionization, it is common for analytes to enter the gas phase accompanied by a charge-carrying ion, and in most cases, this addition is required to enable detection in the mass spectrometer. These small charge carriers may not be influential in solution but can markedly tune the analyte properties in the gas phase. Therefore, measuring their relative influence on the target molecule can assist our understanding of the structure and stability of the analyte. As the formed adducts are usually distinguishable by their mass, differences in the behavior of the analyte resulting from these added species (e.g., structure, stability, and conformational dynamics) can be easily extracted. Here, we use ion mobility mass spectrometry, supported by density functional theory, to investigate how charge carriers (H

Identifiers

PMID36716284
PMCPMC9930111

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.