ArticleCommunications chemistry2020
Observation of an exotic state of water in the hydrophilic nanospace of porous coordination polymers.
Article in Communications chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed, 23 citations in OpenAlex.
- Multivariate Hydrogen-Bonded Organic Frameworks for Optimum Atmospheric Water Harvesting.ACS central science · 2025Article
- Water motifs in zirconium metal-organic frameworks induced by nanoconfinement and hydrophilic adsorption sites.Nature communications · 2024Article
- Mild-Temperature Supercritical Water Confined in Hydrophobic Metal-Organic Frameworks.Journal of the American Chemical Society · 2024Article
- Ultrafast Water H-Bond Rearrangement in a Metal-Organic Framework Probed by Femtosecond Time-Resolved Infrared Spectroscopy.Journal of the American Chemical Society · 2023Article
- Nanointerfaces: Concepts and Strategies for Optical and X-ray Spectroscopic Characterization.ACS physical chemistry Au · 2023Review
- The Consequences of Water Interactions with Nitrogen-Containing Carbonaceous Quantum Dots-The Mechanistic Studies.International journal of molecular sciences · 2022Article
- A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments.Nature communications · 2022Article
- Freezing of few nanometers water droplets.Nature communications · 2021Article
Corrections and comments
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Authors and funding
7 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Fundamental understanding of the confinement of water in porous coordination polymers (PCPs) is important not only with respect to their application, such as in gas storage and separation, but also for exploring confinement effects in nanoscale spaces. Here, we report the observation of water in an exotic state in the well-designed hydrophilic nanopores of PCPs. Single-crystal X-ray diffraction finds that nanoconfined water has an ordered structure that is characteristic in ices, but infrared spectroscopy reveals a significant number of broken hydrogen bonds that is characteristic in liquids. We find that their structural properties are quite similar to those of solid-liquid supercritical water predicted in hydrophobic nanospace at extremely high pressure. Our results will open up not only new potential applications of water in an exotic state in PCPs to control chemical reactions, but also experimental systems to clarify the existence of solid-liquid critical points.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.